Catalytic applications of early/late heterobimetallic complexes

Catalysis Reviews - Science and Engineering

Volumn 54, Issue 1, 2012, Pages 1-40

  Cooper, Benjamin G ^a   Napoline, J Wesley ^a   Thomas, Christine M ^a  

^a BRANDEIS UNIVERSITY   (United States)

Author keywords

Bimetallic; heterobimetallic; mixed metal systems; transition metals

Indexed keywords

BIMETALLIC; BRIDGING LIGANDS; CATALYTIC APPLICATIONS; CATALYTIC TRANSFORMATION; EARLY TRANSITION METALS; HETERO BIMETALLIC COMPLEXES; HETEROBIMETALLICS; LATE TRANSITION METALS; MONOMETALLIC COMPLEX;

METAL COMPLEXES; TRANSITION METAL COMPOUNDS;

TRANSITION METALS;

EID: 84856105763     PISSN: 01614940     EISSN: 15205703     Source Type: Journal    
DOI: 10.1080/01614940.2012.619931     Document Type: Review

References (100)

1. Rodriguez, J.A.; Goodman, D.W. The Nature of the Metal-Metal Bond in Bimetallic Surfaces. Science 1992, 257, 897-903. (Pubitemid 23584338)
2. Gade, L.H. Highly Polar Metal-Metal Bonds In "Early-Late" Heterodimetallic Complexes. Angew. Chem. Int. Ed. 2000, 39, 2658-2678. (Pubitemid 30629184)
3. Stephan, D.W. Early-Late Heterobimetallics. Coord. Chem. Rev. 1989, 95, 41-107.
4. Wheatley, N.; Kalck, P. Structure and Reactivity of Early-Late Heterobimetallic Complexes. Chem. Rev. 1999, 99, 3379-3420.
5. Bullock, R.M.; Casey, C.P. Heterobimetallic Compounds Linked by Heterodifunctional Ligands. Acc. Chem. Res. 1987, 20, 167-173.
6. Ichikawa, M. Catalysis by Supported Metal Crystallites Prepared from Metal Carbonyl Clusters: III. Catalytic Vapor-Phase Hydroformylation of Olefins over Rh, Bimetallic Rh-Co, and Co Crystallites Prepared from the Carbonyl Cluster Compounds Dispersed on Zinc Oxide. J. Catal. 1979, 56, 127-129.
7. Geoffroy, G.L. Synthesis, Molecular-Dynamics, and Reactivity of Mixed-Metal Clusters. Acc. Chem. Res. 1980, 13, 469-476.
8. Guczi, L.; Boskovic, G.; Kiss, E. Bimetallic Cobalt Based Catalysts. Catal. Rev. Sci. Eng. 2010, 52, 133-203.
9. Tauster, S.J.; Fung, S.C.; Garten, R.L. Strong Metal-Support Interactions. Group 8 Noble Metals Supported on Titanium Dioxide. J. Am. Chem. Soc. 1978, 100, 170-175.
10. Min, B.K.; Santra, A.K.; Goodman, D.W. Understanding Silica-Supported Metal Catalysts: Pd/Silica as a Case Study. Catal. Today 2003, 85, 113-124.
11. Jacobs, G.; Patterson, P.M.; Das, T.K.; Luo, M.S.; Davis, B.H. Fischer-Tropsch Synthesis: Effect of Water on Co/Al2O3 Catalysts and XAFS Characterization of Reoxidation Phenomena. Appl. Catal., A 2004, 270, 65-76.
12. Tauster, S.J. Strong Metal Support Interactions-Facts and Uncertainties. ACS Symposium Series 1986, 298, 1-9. (Pubitemid 17504766)
13. Sadeghi, H.R.; Henrich, V.E. Electronic Interactions in the Rhodium/Tio2 System. J. Catal. 1988, 109, 1-11.
14. Kennedy, J.C.; Datye, A.K. Photothermal Heterogeneous Oxidation of Ethanol over Pt/TiO2. J. Catal. 1998, 179, 375-389.
15. Hayek, K.; Fuchs, M.; Klotzer, B.; Reichl, W.; Rupprechter, G. Studies of Metal-Support InteractionsWith "Real" And "Inverted"Model Systems: Reactions of CO and Small Hydrocarbons with Hydrogen on NobleMetals in Contact with Oxides. Top. Catal. 2000, 13, 55-66.
16. Gade, L.H.; Memmler, H.; Kauper, U.; Schneider, A.; Fabre, S.; Bezougli, I.; Lutz, M.; Galka, C.; Scowen, I.J.; McPartlin, M. Cooperative Reactivity of Early-Late Heterodinuclear Transition Metal Complexes with Polar Organic Substrates. Chem. Eur. J. 2000, 6, 692-708.
17. Baranger, A.M.; Bergman, R.G. Cooperative Reactivity in the Interactions of XH Bonds with a Zirconium-Iridium Bridging Imido Complex. J. Am. Chem. Soc. 1994, 116, 3822-3835. (Pubitemid 24980970)
18. Baranger, A.M.; Hollander, F.J.; Bergman, R.G. Synthesis of an Early-Late Heterobimetallic Imido Complex: Cooperative Reactivity with Nitrogen-, Oxygen-, and Sulfur-Hydrogen Bonds and Formation of a Novel Aminophosphine Complex. J. Am. Chem. Soc. 1993, 115, 7890-7891.
19. Cotton, F.A.; James, C.A.; Luck, R.L. Synthesis and Characterization of the 1st Multiply Bonded Heteronuclear Edge-Sharing Bioctahedral Complex, MoWCl4(μ-Cl)(μ-H)(μ-dppm)2. Inorg. Chem. 1991, 30, 4370-4373.
20. Greenwood, B.P.; Forman, S.I.; Rowe, G.T.; Chen, C.-H.; Foxman, B.M.; Thomas, C.M. Multielectron Redox Activity Facilitated by Metal-Metal Interactions in Early/Late Heterobimetallics: Co/Zr Complexes Supported by Phosphinoamide Ligands. Inorg. Chem. 2009, 48, 6251-6260.
21. Qi, J.S.; Schrier, P.W.; Fanwick, P.E.; Walton, R.A. Redox Reactions between Metal Metal Multiple Bonds and Carbon-Disulfide. J. Chem. Soc.-Chem. Commun. 1991, 1737-1739.
22. Bartley, S.L.; Dunbar, K.R. (Re2Cl4(dppm)2)2(μ-TCNQ), a Novel Charge-Transfer Complex Derived from a Donor with a Metal-Metal Multiple Bond. Angew. Chem. Int. Ed. 1991, 30, 448-450.
23. Chisholm, M.H.; Huffman, J.C.; Marchant, N.S. Reactions of M-M Triple Bonds with C-N Triple Bonds-Adduct Formation (M = Mo) and Metathesis (M = W) as Seen in the Reactions between Dimethylcyanamide and Hexaalkoxides of Dimolybdenum and Ditungsten. J. Am. Chem. Soc. 1983, 105, 6162-6163.
24. Ritleng, V.; Chetcuti, M.J. Hydrocarbyl Ligand Transformations on Heterobimetallic Complexes. Chem. Rev. 2007, 107, 797-858. (Pubitemid 46502372)
25. Shima, T.; Suzuki, H. Heterobimetallic Polyhydride Complex Containing Ruthenium and Iridium. Synthesis and Site-Selectivity in the Reaction with Unsaturated Hydrocarbons. Organometallics 2000, 19, 2420-2422.
26. Kalck, P.; Serra, C.; Machet, C.; Broussier, R.; Gautheron, B.; Delmas, G.; Trouve, G.; Kubicki, M. Carbonylation of Ethene to Acrolein in the Presence of the Early-Late Heterobimetallic Complex [AsPh4][(η5-C5Me5)2Zr(μ-S) 2Rh(CO)2]•thf. Organometallics 1993, 12, 1021-1022.
27. Hostetler, M.J.; Butts, M.D.; Bergman, R.G. Scope and Mechanism of Alkene Hydrogenation/Isomerization Catalyzed by Complexes of the Type R2E(CH2)2M(CO)(L) (R = Cp, Me, Ph; E = Phosphorus, Tantalum; M = Rhodium, Iridium; L = CO, PPh3). J. Am. Chem. Soc. 1993, 115, 2743-2752.
28. McCollum, D.G.; Fraser, C.; Ostrander, R.; Rheingold, A.L.; Bosnich, B. Bimetallic Reactivity-General-Synthesis of Binucleating Macrocyclic Ligands Containing 6-Coordinate and 4-Coordinate Sites. Inorg. Chem. 1994, 33, 2383-2392.
29. Man, M.L.; Lam, K.C.; Sit, W.N.; Ng, S.M.; Zhou, Z.; Lin, Z.; Lau, C.P. Synthesis of Heterobimetallic Ru-Mn Complexes and the Coupling Reactions of Epoxides with Carbon Dioxide Catalyzed by These Complexes. Chem. Eur. J. 2006, 12, 1004-1015. (Pubitemid 43148997)
30. Correia, M.C.; Moghieb, A.; Goforth, S.K.; McElwee-White, L. Electrochemical Oxidation of Ethanol Using Heterobimetallic Complexes as an Approach to DEFC Catalysts. ECS Trans. 2009, 19, 13-21.
31. Holm, R.H. Metal-Centered Oxygen Atom Transfer-Reactions. Chem. Rev. 1987, 87, 1401-1449.
32. York, J.T.; Llobet, A.; Cramer, C.J.; Tolman, W.B. Heterobimetallic Dioxygen Activation: Synthesis and Reactivity of Mixed Cu-Pd and Cu-Pt Bis(μ-Oxo) Complexes. J. Am. Chem. Soc. 2007, 129, 7990-7999. (Pubitemid 46998198)
33. Roberts, D.A.; Geoffroy, G.L.; Geoffrey, W.; Stone, F.G.A.; Edward, W.A., Compounds with heteronuclear bonds between transition metals. In Comprehensive Organometallic Chemistry; Pergamon: Oxford, 1982, pp. 763-877.
34. Shibasaki, M.; Yamamoto, Y., Multimetallic Catalysts in Organic Synthesis; Wiley-VCH GmbH & Co. KGaA: Weinheim, 2004.
35. Shibasaki, M.; Sasai, H.; Arai, T. Asymmetric Catalysis with Heterobimetallic Compounds. Angew. Chem. Int. Ed. 1997, 36, 1237-1256.
36. Shibasaki, M.; Yoshikawa, N. Lanthanide Complexes in Multifunctional Asymmetric Catalysis. Chem. Rev. 2002, 102, 2187-2209. (Pubitemid 35377642)
37. Sappa, E.; Tiripicchio, A.; Braunstein, P. Selective Metal-Ligand Interactions in Heterometallic Transition-Metal Clusters. Coord. Chem. Rev. 1985, 65, 219-284.
38. Braunstein, P.; Rose, J.; Edward, W.A.; Stone, F.G.A.; Geoffrey, W., Catalysis and Related Reactions with Compounds Containing Heteronuclear Metal-Metal Bonds. In Comprehensive Organometallic Chemistry II; Elsevier: Oxford, 1995; pp. 351-385.
39. Comstock, M.C.; Shapley, J.R. Hydrocarbyl Ligand Derivatives of Group 6-Group 9 Heterometallic Clusters. Coord. Chem. Rev. 1995, 143, 501-533.
40. Braunstein, P.; Rose, J., Heterometallic clusters for heterogeneous catalysis. In Catalysis by Di-and Polynuclear Metal Cluster Complexes, Adams, R.D.; Cotton, F.A., Eds., Wiley-VCH: New York, NY, 1998, pp. 443-508.
41. Abe, H.; Matsumoto, F.; Alden, L.R.; Warren, S.C.; Abruna, H.D.; DiSalvo, F.J. Electrocatalytic Performance of Fuel Oxidation by Pt3Ti Nanoparticles. J. Am. Chem. Soc. 2008, 130, 5452-5458. (Pubitemid 351612953)
42. Saravanan, G.; Abe, H.; Xu, Y.; Sekido, N.; Hirata, H.; Matsumoto, S.-i.; Yoshikawa, H.; Yamabe-Mitarai, Y. Pt3Ti Nanoparticles: Fine Dispersion on SiO2 Supports, Enhanced Catalytic Co Oxidation, and Chemical Stability at Elevated Temperatures. Langmuir 2010, 26, 11446-11451.
43. Ghosh, T.; Leonard, B.M.; Zhou, Q.; DiSalvo, F.J. Pt Alloy and Intermetallic Phases with V, Cr, Mn, Ni, and Cu: Synthesis as Nanomaterials and Possible Applications as Fuel Cell Catalysts. Chem. Mater. 2010, 22, 2190-2202.
44. Nakata, N.; Sakashita, M.; Komatsubara, C.; Ishii, A. Synthesis, Structure, and Catalytic Activity of Bimetallic Pt-II-Ir-III Complexes Bridged by Cyclooctane-1,2-Dithiolato Ligands. Eur. J. Inorg. Chem. 2010, 447-453.
45. Leelasubcharoen, S.; Zhizhko, P.A.; Kuzmina, L.G.; Churakov, A.V.; Howard, J.A.K.; Nikonov, G.I. Niobium/Rhodium Bimetallic Complexes: Synthesis, Structure, and Catalytic Hydrosilylation of Acetophenone and Benzaldehyde. Organometallics 2009, 28, 4500-4506.
46. Comte, V.; Le Gendre, P.; Richard, P.; Moise, C. TiPHOS(Rh) (+): A Fortuitous Coordination Mode and an Effective Hydrosilylation Bimetallic Catalyst. Organometallics 2005, 24, 1439-1444. (Pubitemid 40448865)
47. Bosch, B.E.; Brummer, I.; Kunz, K.; Erker, G.; Frohlich, R.; Kotila, S. Structural Characterization of Heterodimetallic Zr/Pd and Zr/Rh Catalyst Precursors Containing the C5H4PPh2 Ligand. Organometallics 2000, 19, 1255-1261.
48. Fandos, R.; Hernandez, C.; Otero, A.; Rodriguez, A.; Ruiz, M.J.; Terreros, P. Early-Late Heterobimetallic Alkoxides as Model Systems for Late-Transition-Metal Catalysts Supported on Titania. Chem. Eur. J. 2003, 9, 671-677.
49. Ojeda, M.; Fandos, R.; Fierro, J.L.G.; Otero, A.; Pastor, C.; Rodriguez, A.; Ruiz, M.J.; Terreros, P. Synthesis and Reactivity of Heterometallic RhO-M (M = Si, Ti) Complexes Memory Effect in Their Catalytic Performance in Co Hydrogenation. J. Mol. Catal. A: Chem. 2006, 247, 44-51.
50. Fandos, R.; Otero, A.; Rodriguez, A.; Terreros, P.; Aullon, G.; Alvarez, S. A New Titanium Alkoxide-Thiolate Complex as a Versatile Heterofunctional Metalloligand. Eur. J. Inorg. Chem. 2009, 1079-1085.
51. Man, M.L.; Zhou, Z.Y.; Ng, S.M.; Lau, C.P. Synthesis, Characterization and Reactivity of Heterobimetallic Complexes (η5-C5R5)Ru(CO)(μ-dppm)M(CO) 2(η5-C5H5) (R = H, CH3; M = Mo, W). Interconversion of Hydrogen/Carbon Dioxide and Formic Acid by These Complexes. Dalton Trans. 2003, 3727-3735.
52. Kato, H.; Seino, H.; Mizobe, Y.; Hidai, M. Syntheses and Reactivities of Hydrosulfido-or Sulfido-Bridged Heterobimetallic Complexes Containing Group 6 and Group 9 Metals. Dalton Trans. 2002, 1494-1499. (Pubitemid 35206639)
53. Miyazaki, T.; Tanabe, Y.; Yuki, M.; Miyake, Y.; Nishibayashi, Y. Synthesis of Group IV (Zr, Hf)-Group VIII (Fe, Ru) Heterobimetallic Complexes Bearing Metallocenyl Diphosphine Moieties and Their Application to Catalytic Dehydrogenation of Amine-Boranes. Organometallics 2011, 30, 2394-2404.
54. Braunstein, P.; Durand, J.; Morise, X.; Tiripicchio, A.; Ugozzoli, F. Catalytic Dehydrogenative Coupling of Stannanes by Alkoxysilyl Heterobimetallic Complexes: Influence of the Assembling Ligand. Organometallics 2000, 19, 444-450.
55. Braunstein, P.; Morise, X. Reactivity of Heterobimetallic Alkoxysilyl and Siloxy Complexes in the Catalytic Dehydrogenative Coupling of Tin Hydrides. Organometallics 1998, 17, 540-550. (Pubitemid 128566064)
56. Braunstein, P.; Morise, X.; Blin, J. Reactivity of Heterobimetallic Alkoxysilyl and Siloxyl Complexes in the Dehydrogenative Coupling of Stannanes. Chem. Commun. 1995, 1455-1456.
57. Ye, S.; Leong, W.K. Synthesis and Structure of Some Ruthenium-Rhenium Heterodinuclear Complexes and Their Catalytic Activity in the Addition of Carboxylic Acids to Phenylacetylene. J. Organomet. Chem. 2006, 691, 1216-1222. (Pubitemid 43234363)
58. Le Gendre, P.; Comte, V.; Michelot, A.; Moïse, C. Synthesis of Enol Esters Catalysed by 'Early-Late' Ti-Ru Complexes. Inorg. Chim. Acta 2003, 350, 289-292.
59. Liu, X.; Henderson, J.A.; Sasaki, T.; Kishi, Y. Dramatic Improvement in Catalyst Loadings and Molar Ratios of Coupling Partners for Ni/Cr-Mediated Coupling Reactions: Heterobimetallic Catalysts. J. Am. Chem. Soc. 2009, 131, 16678-16680.
60. Braunstein, P.; Clerc, G.; Morise, X. Cyclopropanation and Diels-Alder Reactions Catalyzed by the First Heterobimetallic Complexes with Bridging Phosphinooxazoline Ligands. New J. Chem. 2003, 27, 68-72. (Pubitemid 36124028)
61. Slaughter, L.M.; Wolczanski, P.T. Ti(μ:η1,η1-OCMe2CH2PPh2)3Rh Has a Cylindrically Symmetric Triple Bond. Chem. Commun. 1997, 2109-2110.
62. Morgan, J.P.; Kundu, K.; Doyle, M.P. A Readily Prepared Neutral Heterobimetallic Titanium(IV)-Rhodium(I) Catalyst for Intramolecular Hydroacylation. Chem. Commun. 2005, 3307-3309. (Pubitemid 41018859)
63. Zhou, W.; Napoline, J.W.; Thomas, C.M. A Catalytic Application of Co/Zr Heterobimetallic Complexes: Kumada Coupling of Unactivated Alkyl Halides with Alkyl Grignard Reagents. Eur. J. Inorg. Chem. 2011, 2011, 2029-2033.
64. Setty, V.N.; Zhou, W.; Foxman, B.M.; Thomas, C.M. Subtle Differences between Zr and Hf in Early/Late Heterobimetallic Complexes with Cobalt. Inorg. Chem. 2011, 50, 4647-4655.
65. Lindenberg, F.; Shribman, T.; Sieler, J.; Hey-Hawkins, E.; Eisen, M.S. Dinuclear Phosphido-and Arsenido-Bridged Early/Late Transition Metal Complexes. Efficient Catalysts for Ethylene Polymerization. J. Organomet. Chem. 1996, 515, 19-25. (Pubitemid 126166844)
66. Shribman, T.; Kurz, S.; Senff, U.; Lindberg, F.; Hey-Hawkins, E.; Eisen, M.S. Catalytic Polymerization of Propylene by Heterobimetallic Bridged Early/Late Transition Metal Complexes. J. Mol. Catal. A: Chem. 1998, 129, 191-198. (Pubitemid 28187375)
67. Kuwabara, J.; Takeuchi, D.; Osakada, K. Early-Late Heterobimetallic Complexes as Initiator for Ethylene Polymerization. Cooperative Effect of Two Metal Centers to Afford Highly Branched Polyethylene. Chem. Commun. 2006, 3815-3817. (Pubitemid 44394142)
68. Takayama, C.; Yamaguchi, Y.; Mise, T.; Suzuki, N. Electronic Effects in Homogeneous Ziegler-Natta Catalysts: Zr-Rh Early-Late Heterobimetallic Complexes. Dalton Trans. 2001, 948-953.
69. Ishino, H.; Takemoto, S.; Hirata, K.; Kanaizuka, Y.; Hidai, M.; Nabika, M.; Seki, Y.; Miyatake, T.; Suzuki, N. Preparation and Properties of Molybdenum and Tungsten Dinitrogen Complexes. Part 72. Olefin Polymerization Catalyzed by Titanium-Tungsten Heterobimetallic Dinitrogen Complexes. Organometallics 2004, 23, 4544-4546.
70. Nikitinskii, A.V.; Bochkarev, L.N.; Voronin, R.V.; Khorshev, S.Y.; Kurskii, Y.A.; Bochkarev, M.N. Synthesis of Heterobimetallic Zinc Complexes and Their Catalytic Properties in Reactions of CO2 with Cyclohexene Oxide. Russ. J. Gen. Chem. 2004, 74, 1194-1196. (Pubitemid 41295795)
71. Nikitinskii, A.V.; Bochkarev, L.N.; Khorshev, S.Y.; Bochkarev, M.N. Synthesis of Heterobimetallic Lanthanide Tert-Butoxides and Their Catalytic Properties in Reactions of CO2 with Epoxides. Russ. J. Gen. Chem. 2004, 74, 1197-1200. (Pubitemid 41295796)
72. Baranger, A.M.; Hanna, T.A.; Bergman, R.G. Transfer of Oxygen and Sulfur from Organic-Molecules to a Zr-Ir Bond-Evidence for an Unusually Rapid Atom Abstraction Reaction. J. Am. Chem. Soc. 1995, 117, 10041-10046.
73. Fulton, J.R.; Hanna, T.A.; Bergman, R.G. Insertion of Nitriles into a Zirconium-Iridium Heterobimetallic Complex: A Mechanistic Study. Organometallics 2000, 19, 602-614.
74. Hanna, T.A.; Baranger, A.M.; Bergman, R.G. Reaction of Carbon Dioxide and Heterocumulenes with an Unsymmetrical Metal-Metal Bond. Direct Addition of Carbon Dioxide across a Zirconium-Iridium Bond and Stoichiometric Reduction of Carbon Dioxide to Formate. J. Am. Chem. Soc. 1995, 117, 11363-11364.
75. Casey, C.P. Synthesis and Reactions of Directly Bonded Zirconium-Ruthenium Heterobimetallic Complexes. J. Organomet. Chem. 1990, 400, 205-221.
76. Oishi, M.; Kato, T.; Nakagawa, M.; Suzuki, H. Synthesis and Reactivity of Early-Late Heterobimetallic Hydrides of Group 4 Metals and Iridium Supported by Mono(η5-C5Me5) Ancillary Ligands: Bimetallic Carbon-Hydrogen Bond Activation. Organometallics 2008, 27, 6046-6049.
77. Oishi, M.; Suzuki, H. Zirconocene-Iridium Hydrido Complexes: Arene Carbon-Hydrogen Bond Activation and Formation of a Planar Square Zr2Ir2 Complex. Inorg. Chem. 2009, 48, 2349-2351.
78. Greenwood, B.P.; Rowe, G.T.; Chen, C.-H.; Foxman, B.M.; Thomas, C.M. Metal-Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at Both Zr and Co. J. Am. Chem. Soc. 2010, 132, 44-45.
79. Thomas, C.M.; Napoline, J.W.; Rowe, G.T.; Foxman, B.M. Oxidative Addition Across Co/Zr Multiple Bonds in Early/Late Heterobimetallic Complexes. Chem. Commun. 2010, 46, 5790-5792.
80. Braunstein, P.; Chetcuti, M.J.; Welter, R. Bimetallic-Induced Tail-to-Tail Dimerization and C-H Activation of Methyl Acrylate. Chem. Commun. 2001, 2508-2509. (Pubitemid 33124109)
81. Ohki, Y.; Matsuura, N.; Marumoto, T.; Kawaguchi, H.; Tatsumi, K. Heterolytic Cleavage of Dihydrogen Promoted by Sulfido-Bridged Tungsten-Ruthenium Dinuclear Complexes. J. Am. Chem. Soc. 2003, 125, 7978-7988. (Pubitemid 36782175)
82. West, N.M.; Labinger, J.A.; Bercaw, J.E. Heterobimetallic Complexes of Rhenium and Zinc: Potential Catalysts for Homogeneous Syngas Conversion. Organometallics 2011, 30, 2690-2700.
83. Khorasani-Motlagh, M.; Safari, N.; Pamplin, C.B.; Patrick, B.O.; James, B.R. Reaction of H2S with MoRu(CO)6(dppm)2 to Give H2 and a Bridged-Sulfide Product Via Hydrido-Sulfhydryl Intermediates (dppm = Ph2PCH2PPh2). Can. J.Chem. 2006, 84, 330-336.
84. Khorasani-Motlagh, M.; Safari, N.; Pamplin, C.B.; Patrick, B.O.; James, B.R. Oxidative Addition of Thiols to (CO)3Mo(μ-dppm)2Ru(CO)3 with Formation of Hydrido, Bridged-Thiolate Complexes (dppm = Ph2PCH2PPh2). Inorg. Chim. Acta 2010, 363, 779-783.
85. Khorasani-Motlagh, M.; Safari, N.; Pamplin, C.B.; Patrick, B.O.; James, B.R. Oxidative Addition of Halogens to MoRu(CO)6(dppm)2. Inorg. Chem. Commun. 2003, 6, 1175-1179.
86. Davies, J.E.; Mays, M.J.; Raithby, P.R.; Sarveswaran, K.; Solan, G.A. Formation of Carbene and Cyclopentadienyl Ligands from Phenylacetylene Via Oligomerisation and C C Bond Scission at a Mixed-Metal W-Co Centre. Chem. Commun. 2000, 1313-1314. (Pubitemid 30484230)
87. Rios, R.; Pericas, M.A.; Moyano, A. Heterobimetallic (Co-W) Intermolecular Pauson-Khand Reactions: Scope and Selectivity. Tetrahedron Lett. 2002, 43, 4903-4906. (Pubitemid 34663773)
88. Rios, R.; Paredes, S.; Pericas, M.A.; Moyano, A. Chiral Cyclopentadiene-Mediated Approach to Enantio Selective Heterobimetallic Pauson-Khand Reactions. J. Organomet. Chem. 2005, 690, 358-362. (Pubitemid 40091519)
89. Sisak, A.; Halmos, E. Reactions of Early-Late Heterobimetallics with Oxiranes: New Examples for Cooperative Reactivity. J. Organomet. Chem. 2007, 692, 1817-1824. (Pubitemid 46399738)
90. Brenner, E.; Chetcuti, M.J.; Dridi, I.; Welter, R. Reactions of Nickel-Group 6 Complexes with a Bulky Terminal Alkyne to Afford Alkyne-Carbonyl Coupled Products: X-Ray Structure of the Heterobimetallic Nickelacyclobutenone Complex (η5-C5Me5)Ni{μ-η1, η3-C(H)=C(CPh2(OMe))-C(O)}-Mo(CO) 2(η5-C5H4Me) (Ni-Mo). J. Organomet. Chem. 2007, 692, 5097-5102. (Pubitemid 47430139)
91. Cornelissen, C.; Erker, G.; Kehr, G.; Frohlich, R. Chemistry of Metal-Metal-Bonded Early-Late Heterobimetallics: Cooperative Reactions of Functional Groups at a Persistent Organometallic Zr-Rh Framework. Organometallics 2005, 24, 214-225. (Pubitemid 40168882)
92. Tsutsuminai, S.; Komine, N.; Hirano, M.; Komiya, S. Synthesis and Reactions of Heterodinuclear Organoplatinum Complexes Having an Unsymmetrical PN Ligand. Organometallics 2003, 22, 4238-4247.
93. Braunstein, P.; Durand, J.; Knorr, M.; Strohmann, C. Heterobimetallic Intermediates in Alkene Insertion Reactions into a Pd-Acetyl Bond. Chem. Commun. 2001, 211-212. (Pubitemid 32115672)
94. Knorr, M.; Strohmann, C. Reactivity of Silyl-Substituted Heterobimetallic Iron-Platinum Hydride Complexes Towards Unsaturated Molecules, I Alkyne Insertions into the Platinum-Hydride Bond, Phosphane-Induced σ-Alkenyl-μ-Vinylidene Rearrangements and Formation of μ-Isonitrile Complexes. Eur. J. Inorg. Chem. 2000, 2000, 241-252.
95. Knorr, M.; Jourdain, I.; Villafane, F.; Strohmann, C. Reactivity of Silyl-Substituted Heterobimetallic Iron-Platinum Hydride Complexes Towards Unsaturated Molecules: Part II. Insertion of Trifluoropropyne and Hexafluorobutyne into the Platinum-Hydride Bond. J. Organomet. Chem. 2005, 690, 1456-1466. (Pubitemid 40320495)
96. Jourdain, I.; Vieille-Petit, L.; Clement, S.; Knorr, M.; Villafane, F.; Strohmann, C. Reactivity of Silyl-Substituted Heterobimetallic Iron-Platinum Hydride Complexes: Part III. Alkyne Insertions into the Platinum-Hydride Bond and Competition between μ-Vinylidene and Dimetallacyclopentenone Formation. Inorg. Chem. Commun. 2006, 9, 127-131.
97. Braunstein, P.; Knorr, M.; Reinhard, G.; Schubert, U.; Stahrfeldt, T. Novel Metalto-Metal Silyl-Migration Reactions in Heterometallic Complexes. Chem. Eur. J. 2000, 6, 4265-4278.
98. Messaoudi, A.; Deglmann, P.; Braunstein, P.; Hofmann, P. Investigations on a Novel Silyl Transfer Reaction in Heterodimetallic Chemistry Inorg. Chem. 2007, 46, 7899-7909.
99. Knorr, M.; Jourdain, I.; Crini, G.; Frank, K.; Sachdev, H.; Strohmann, C. Synthesis, Reactivity and Molecular Structures of Bis(Diphenylphosphanyl) Methane-Bridged Heterobimetallic Iron-Platinum Isocyanide Complexes: Breaking and Formation of Metal-Metal Bonds. Eur. J. Inorg. Chem. 2002, 2419-2426.
100. Hossain, M.; Lin, H.M.; Wang, C.M.; Shyu, S.G. Synthesis and Characterization of Single Thiolato-Bridged Heterodinuclear Complexes: Irreversible Isomerization of Cp(CO)2W(μ-SPh)(μ-Cl)Ru(Ru(CO)(Cl)(PPh3) to Cp(CO)2W(μ-SPh)(μ-Cl)Ru(CO)2(PPh3) Via Chloride and Carbonyl Ligand Migration. Organometallics 2009, 28, 264-269.