Synthesis, structure, and catalytic activity of bimetallic pt II-IrIII complexes bridged by cyclooctane- 1,2-dithiolato ligands

European Journal of Inorganic Chemistry

Volumn , Issue 3, 2010, Pages 447-453

  Nakata, Norio ^a   Sakashita, Masahiro ^a   Komatsubara, Chizuru ^a   Ishii, Akihiko ^a  

^a SAITAMA UNIVERSITY   (Japan)

Author keywords

Heterometallic complexes; Hydrosilylation; Iridium; Platinum; S ligands

Indexed keywords

BINARY ALLOYS; CATALYST ACTIVITY; CHELATION; HYDROSILYLATION; LIGANDS; PLATINUM ALLOYS; PLATINUM COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

BIMETALLICS; CATIONICS; CYCLOOCTANES; DITHIOLATO LIGANDS; HETERO BIMETALLIC COMPLEXES; HETEROMETALLIC COMPLEXES; HYDROSILYLATIONS; S LIGANDS; SYNTHESISED; TRANS-C;

IRIDIUM COMPOUNDS;

EID: 74549170377     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200900958     Document Type: Article

References (53)

1. For general reviews, see: a) P. Braunstein, J. Rose in Comprehensive Organometallic Chemistry II (Eds.: G. Wilkinson, F. G. A. Stone, E. W. Abel), Pergamon, Oxford, 1995, vol.10, p. 351;
2. b) R. D. Adams, M. J. Chetcuti in Comprehensive Organometallic Chemistry II (Eds.: G. Wilkinson, F. G. A. Stone, E. W. Abel), Pergamon, Oxford, 1995, vol.10, p. 1, p. 23;
3. (c) for the chemistry of heteronuclear clusters and. multirnetallic catalysts, see: R. D. Adams, W. A. Herrmann, Polyhedron 1988, 7, 2251-2253;
4. (d) N. Wheatley, P. Kalck, Chem. Rev. 1999, 99, 3379-3403.
5. a) D.W. Stephan, Coord. Chem. Rev. 1989, 95, 41-107;
6. b) M. D. Janssen, D. M. Grove, G. Van Koten, Prog. Inorg. Chem. 1997, 46, 97-149;
7. (c) M. Y. Darensbourg, M. Pala, S. A. Houliston, K. P. Kidwell, D. Spencer, S. S. Chojnacki, J. H. Reibenspies, Inorg. Chem. 1992, 31, 1487-1493;
8. (d) V. W.-W. Yam, K. M. C. Wong, K.-K. Cheung, Organometallics 1997,16, 1729-1734;
9. e) R. Rousseau, D. W. Stephan, Organometallics 1991, 10, 3399-3403.
10. T. T. Nadasdi, D. W. Stephan, Inorg. Chem. 1994, 33, 1532-1538 and references cited, therein.
11. a) J. Vicente, M. T. Chicote, S. Huertas, D. Bautista, P. G. Jones, A. K. Fischer, Inorg. Chem. 2001, 40, 2051-2057;
12. b) J. Vicente, M. T. Chicote, S. Huertas, P. G. Jones, A. K. Fischer, Inorg. Chem. 2001, 40, 6193-6200;
13. (c) J. Forniés-Cámer, A. M. Masdeu-Bultó, C. Claver, Inorg. Chem. Commun. 2002, 5, 351-354;
14. (d) R. Y. C. Shin, J. J. Vittal, Z.-Y. Zhou, L. L. Koh, L. Y. Goh, Inorg. Chim. Acta 2003, 352, 220-228;
15. e) S. M. Aucott, H. L. Milton, S. D. Robertson, A. M. Z. Slawin, J. D. Woollins, Dalton Trans. 2004, 3347-3352;
16. f) R. Y. C. Shin, G. K. Tan, L. L. Koh, L. Y. Goh, R. D. Webster, Organometallics 2004, 23, 6108-6115;
17. g) Y.-D. Chen, L.-Y. Zhang, L.-X. Shi, Z.-N. Chen, Inorg. Chem. 2004, 43, 7493-7501;
18. h) R. Y. C. Shin, M. E. Teo, G. K. Tan, L. L. Koh, J. J. Vittal, L. Y. Goh, K. S. Murray, B. Moubaraki, X.-Y. Zhou, Organometallics 2005, 24, 4265-6273;
19. (i) S. Takemoto, D. Shimadzu, K. Kamikawa, H. Matsuzaka, R. Nomura, Organometallics 2006, 25, 982-988;
20. j) J. Vicente, P. González-Herrero, M. Pérez-Cadenas, P. G. Jones, D. Bautista, Inorg. Chem. 2007, 46, 4718-4732;
21. k) R. Y. C. Shin, V. W L. Ng, L. L. Koh, G. K. Tan, L. Y. Goh, R. D. Webster, Organometallics 2007,26, 4555-4561;
22. (l) S. D. Robertson, A. M. Z. Siawin, J. D. Woollins, Eur. J. Inorg. Chem. 2007, 247-253;
23. (m) J. L. Hess, H. L. Conder, K. N. Green, M. Y. Daresbourg, Inorg. Chem. 2008, 47, 2056-2063;
24. n) J. Vicente, P. González-Herrero, Y. García- Sánchez, D. Bautista, Inorg. Chem. 2008, 47, 10662-10673.
25. J. Forniés-Cámer, A. M. Masdeu-Bultó, C. Claver, C. J. Cardin, Inorg. Chem. 1998, 37, 2626-2632.
26. J. Forniés-Cámer, A.M. Masdeu-Bultó, C. Claver, C. Tejel, M. A. Ciriano, C. J. Cardin, Organometallics 2002, 21, 2609-2618.
27. J. Forniés-Cámer, C. Claver, A. M. Masdeu-Bultó, C. J. Cardin, J. Organomet. Chem. 2002, 662, 188-191.
28. S. M. Aucott, D. Duerden, Y. Li, A. M. Z. Slawin, J. D. Woollins, Chem. Eur. J. 2006, 12, 5495-5504.
29. A. Ishii, M. Suzuki, T. Sone, N. Nakata, Phosphorus Sulfur Silicon Relat. Elem. 2009, 184, 1184-1205.
30. A. Ishii, A. Ono, N. Nakata, J. Sulfur Chem. 2009, 30, 236-244.
31. For a recent application of trans-cyclooctane-l,2-dithiol, see: A. Ishii, T. Toda, N. Nakata, T. Matsuo, J. Am. Chem. Soc.2009, 131, 13566-13567.
32. A. Ishii, S. Kashiura, Y. Hayashi, W. Weigand, Chem. Eur. J. 2007, 13, 4326-4333.'
33. N. Nakata, S. Yamamoto, W. Hashima, A. Ishii, Chem. Lett. 2009, 38, 400-401.
34. S. M. Aucott, P. Kilian, S. D. Robertson, A. M. Z. Slawin, J. D. Woollins, Chem. Eur. J. 2006, 12, 895-902.
35. F. Estudiante-Negrete, R. Redón, S. Hernández-Ortega, R. A. Toscano, D. Morales-Morales, Inorg. Chim. Acta 2007, 360, 1651-1660.
36. S. M. Aucott, H. L. Milton, S. D. Robertson, A. M. Z. Slawin, G. D. Walker, J. D. Woollins, Chem. Eur. J. 2004, 10, 1666-1676.
37. Y.-F. Han, Y.-B. Huang, Y.-J. Lin, G.-X. Jin, Organometallics 2008, 27, 961-966.
38. M. Gorol, H. W. Roesky, M. Noltemeyer, H.-G. Schmidt, Eur. J. Inorg. Chem. 2005, 4840-4844.
39. B. Marciniec in Comprehensive Handbook on Hydrosilylation, Pergamon, Oxford, 1992, p. 130.
40. J. W. Faller, D. G. D'Alliessi, Organometallics 2002, 21, 1743-1746.
41. For recent examples of highly ß-(Z)-selective, Ir-catalyzed hydrosilylations, see: a) V. S. Sridevi, W. Y. Fan, W. K. Leong, Organometallics 2007, 26, 1157-1160;
42. b) Y. Miyake, E. Isomura, M. Iyoda, Chem. Lett. 2006, 35, 836-837;
43. (c) M. Viciano E. Mas-Marza, M. Sanau, E. Peris, Organometallics 2006, 25, 3063-3069;
44. (d) E. Mas-Marza, M. Sanau, E. Peris, Organometallics 2006, 25, 3713-3720;
45. e) E. Mas-Marza, M. Sanau, E. Peris, Inorg. Chem. 2005, 44, 9961-9967.
46. a) J. F. Harrod, A. J. Chalk, I. Wender, P. Pino in Organic Synthesis via Metal Carbonyls, Wiley, New York, 1977, vol.2, p. 673;
47. b) M. A. Schroeder, M. S. Wrighton, J. Organomet. Chem. 1977, 128, 345-358.
48. R. H. Crabtree, New J. Chem. 2003, 27, 771-772.
49. M.-J. Fernandez, P.M. Maitlis, J. Chem. Soc, Dalton 'Trans. 1984, 2063-2066.
50. a) E. Lukevics, R. Ya. Sturkovich, O. A. Pudova, J. Organomet. Chem. 1985, 292, 151-158;
51. b) E. Lukevics, V. V. Dirnens, Y. S. Goldberg, E. E. Liepinsh, J. Organomet. Chem. 1986, 316, 249-254.
52. G. M. Sheldrick, SADABS: Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Göttingen, Germany, 1996.
53. G. M. Sheldrick, SHELXTL 5.10 for Windows NT: Structure Determination Software Programs, Bruker Analytical X-ray Systems, Inc., Madison, WI, 1997.