-
3
-
-
33748805466
-
-
(a) Figueroa, J. S.; Melnick, J. G.; Parkin, G. Inorg. Chem. 2006, 45, 7056.
-
(2006)
Inorg. Chem
, vol.45
, pp. 7056
-
-
Figueroa, J.S.1
Melnick, J.G.2
Parkin, G.3
-
4
-
-
0033578646
-
-
(b) Hill, A. F.; Owen, G. R.; White, A. J. P.; Williams, D. J. Angew. Chem., Int. Ed. 1999, 38, 2759.
-
(1999)
Angew. Chem., Int. Ed
, vol.38
, pp. 2759
-
-
Hill, A.F.1
Owen, G.R.2
White, A.J.P.3
Williams, D.J.4
-
5
-
-
57549091568
-
-
(c) Sircoglou, M.; Bontemps, S.; Bouhadir, G.; Saffon, N.; Miqueu, K.; Gu, W.; Mercy, M.; Chen, C.-H.; Foxman, B. M.; Maron, L.; Ozerov, O. V.; Bourissou, D. J. Am. Chem. Soc. 2008, 130, 16729.
-
(2008)
J. Am. Chem. Soc
, vol.130
, pp. 16729
-
-
Sircoglou, M.1
Bontemps, S.2
Bouhadir, G.3
Saffon, N.4
Miqueu, K.5
Gu, W.6
Mercy, M.7
Chen, C.-H.8
Foxman, B.M.9
Maron, L.10
Ozerov, O.V.11
Bourissou, D.12
-
6
-
-
38149136409
-
-
(d) Bontemps, S.; Sircoglou, M.; Bouhadir, G.; Puschmann, H.; Howard, J. A. K.; Dyer, P, W.; Miqueu, K.; Bourissou, D. Chem.-Eur. J. 2008, 14, 731-740.
-
(2008)
Chem.-Eur. J
, vol.14
, pp. 731-740
-
-
Bontemps, S.1
Sircoglou, M.2
Bouhadir, G.3
Puschmann, H.4
Howard, J.A.K.5
Dyer, P.W.6
Miqueu, K.7
Bourissou, D.8
-
7
-
-
36549064306
-
-
(e) Sircoglou, M.; Bontemps, S.; Mercy, M.; Saffon, N.; Takahashi, M.; Bouhadir, G.; Maron, L.; Bourissou, D. Angew. Chem., Int. Ed. 2007, 46, 8583.
-
(2007)
Angew. Chem., Int. Ed
, vol.46
, pp. 8583
-
-
Sircoglou, M.1
Bontemps, S.2
Mercy, M.3
Saffon, N.4
Takahashi, M.5
Bouhadir, G.6
Maron, L.7
Bourissou, D.8
-
10
-
-
0001681755
-
-
(a) Ferguson, G, S.; Wolczanski, P. T, Organometallics 1985, 4, 1601.
-
(1985)
Organometallics
, vol.4
, pp. 1601
-
-
Ferguson, G.S.1
Wolczanski, P.T.2
-
12
-
-
0000820430
-
-
Ferguson, G. S.; Wolczanski, P. T.; Párkányi. M. C.; Zonncvyille, M, C. Organometallics 1988, 7, 1967.
-
(c) Ferguson, G. S.; Wolczanski, P. T.; Párkányi. M. C.; Zonncvyille, M, C. Organometallics 1988, 7, 1967.
-
-
-
-
13
-
-
0001515640
-
-
(d) Baxter, S. M.; Ferguson, G. S.; Wolczanski, P. T. J. Am. Chem. Soc. 1988, 110, 4231.
-
(1988)
J. Am. Chem. Soc
, vol.110
, pp. 4231
-
-
Baxter, S.M.1
Ferguson, G.S.2
Wolczanski, P.T.3
-
14
-
-
33646354387
-
-
(a) Nagashima, H.; Sue, T.; Oda, T.; Kanemitsu, A.; Matsumoto, T.; Motoyama, Y.; Sunada, Y. Organomelallics 2006, 25, 1987.
-
(1987)
Organomelallics
, vol.2006
, pp. 25
-
-
Nagashima, H.1
Sue, T.2
Oda, T.3
Kanemitsu, A.4
Matsumoto, T.5
Motoyama, Y.6
Sunada, Y.7
-
15
-
-
33745131741
-
-
(b) Sunada, Y.; Sue, T.; Matsumoto, T.; Nagashima, H. J. Organomet. Chem. 2006, 691, 3176.
-
(2006)
J. Organomet. Chem
, vol.691
, pp. 3176
-
-
Sunada, Y.1
Sue, T.2
Matsumoto, T.3
Nagashima, H.4
-
17
-
-
65349099949
-
-
(d) Tsutsumi, H.; Sunada, Y.; Shiota, Y.; Yoshizawa, K.; Nagashima, H. Organometallics 2009, 28, 1988.
-
(1988)
Organometallics
, vol.2009
, pp. 28
-
-
Tsutsumi, H.1
Sunada, Y.2
Shiota, Y.3
Yoshizawa, K.4
Nagashima, H.5
-
21
-
-
0001421865
-
-
(b) Poetschke, N.; Nieger, M.; Khan, M. A.; Niecke, E.; Ashby, M. T. Inorg. Chem. 1997, 56, 4087.
-
(1997)
Inorg. Chem
, vol.56
, pp. 4087
-
-
Poetschke, N.1
Nieger, M.2
Khan, M.A.3
Niecke, E.4
Ashby, M.T.5
-
22
-
-
67649857069
-
-
Additional experimental details are included in the Supporting Information for this manuscript.
-
Additional experimental details are included in the Supporting Information for this manuscript.
-
-
-
-
23
-
-
6844239208
-
-
- couple is -0.14 V vs ferrocene (in MeCN) as reported in; Connelly, N. G.; Geiger, W. E. Chem. Rev. 1996, 96, 877-910.
-
- couple is -0.14 V vs ferrocene (in MeCN) as reported in; Connelly, N. G.; Geiger, W. E. Chem. Rev. 1996, 96, 877-910.
-
-
-
-
24
-
-
2842537224
-
-
I2 reacts stoichiometrically with LiN(PPh2) 2 to effect P-P coupling; Braunstein, P, Hasselbring, R, Tiripicchio, A, Ugozzoli, F. J. Chem. Soc, Chem. Commun. 1995, 37-38. We have also confirmed that I2 is consumed quantitatively by both our phosphinoamines and our zirconium phosphino-amide complexes. Stoichiometric reaction of Ph2PNHiPr with I2 in C6D6 leads to complete consumption of both I2 (based on disappearance of the diagnostic purple color) and Ph 2PNHiPr (based on disappearance of its 31P NMR signal) to form a highly insoluble red/orange material. Likewise, stoichiometric reaction of 2 with 12 leads to complete consumption of both materials and appearance of new phosphorus-containing products
-
2 leads to complete consumption of both materials and appearance of new phosphorus-containing products.
-
-
-
-
25
-
-
84869349073
-
-
1H NMR features to those of 5 in the crude NMR of this reaction.
-
1H NMR features to those of 5 in the crude NMR of this reaction.
-
-
-
-
26
-
-
84869366166
-
-
Examples of discrepancies in covalent radii reported in the literature; (a) 1.75 Å +1.26 Å = 3.01 Å (for Is, Co) or 1.75 Å + 1.50 Å = 3.25 Å; Cordero, B.; Gómez, V.; Platcro-Prats, A. E.; Rcvés, M.; Echeverría, J.; Crcmadcs, E.; Barragán, F.; Alvarez, S. Dalton Trans. 2008, 2832.
-
Examples of discrepancies in covalent radii reported in the literature; (a) 1.75 Å +1.26 Å = 3.01 Å (for Is, Co) or 1.75 Å + 1.50 Å = 3.25 Å; Cordero, B.; Gómez, V.; Platcro-Prats, A. E.; Rcvés, M.; Echeverría, J.; Crcmadcs, E.; Barragán, F.; Alvarez, S. Dalton Trans. 2008, 2832.
-
-
-
-
27
-
-
58449128738
-
-
1.54 Å + 1.11 Å = 2.65 Å: Pyykkö, P.; Atsumi, M. Chem.-Eur. J. 2009, 15, 186.
-
(b) 1.54 Å + 1.11 Å = 2.65 Å: Pyykkö, P.; Atsumi, M. Chem.-Eur. J. 2009, 15, 186.
-
-
-
-
28
-
-
84869373186
-
-
1.45 Å + 1.16 Å = 2.61 Å; Pauling, L. The Nature of the Chemical Bond. 3rd ed.; Cornell University Press; Ithaca, NY. 1960.
-
(c) 1.45 Å + 1.16 Å = 2.61 Å; Pauling, L. The Nature of the Chemical Bond. 3rd ed.; Cornell University Press; Ithaca, NY. 1960.
-
-
-
-
29
-
-
84869344959
-
-
1.56 Å + 1.33 Å = 2.89 Å; Cambridge Structural Database, http://www.ccdc.cam.ac.uk/products/csd/radii/table.php4#symbol.
-
(d) 1.56 Å + 1.33 Å = 2.89 Å; Cambridge Structural Database, http://www.ccdc.cam.ac.uk/products/csd/radii/table.php4#symbol.
-
-
-
-
30
-
-
84869349071
-
-
If the Co-Co (2.506 Å) and Zr-Zr (3.179 A) distances in elemental cobalt and zirconium metal are divided by 2 to extract a typical covalent radius in a metal-metal bond, we obtain 1.59 Å + 1.25 Å=2.84 A; In Table of Interatomic Distances and Configuration in Molecules and Ions, Supplement 1956-1959, Special publication No. 18; Sutton, L. E., Ed.; Chemical Society; London, U.K., 1965.
-
(e) If the Co-Co (2.506 Å) and Zr-Zr (3.179 A) distances in elemental cobalt and zirconium metal are divided by 2 to extract a typical covalent radius in a metal-metal bond, we obtain 1.59 Å + 1.25 Å=2.84 A; In Table of Interatomic Distances and Configuration in Molecules and Ions, Supplement 1956-1959, Special publication No. 18; Sutton, L. E., Ed.; Chemical Society; London, U.K., 1965.
-
-
-
-
31
-
-
0032578156
-
-
Jansen, G.; Schubart, M.; Findeis, B.; Gade, L. H.; Scowen, I. J.; McPartlin, M. J. Am. Chem. Soc. 1998, 120, 7239.
-
(1998)
J. Am. Chem. Soc
, vol.120
, pp. 7239
-
-
Jansen, G.1
Schubart, M.2
Findeis, B.3
Gade, L.H.4
Scowen, I.J.5
McPartlin, M.6
-
33
-
-
0043236213
-
-
Betley, T. A.; Peters, J, C. J. Am. Chem. Soc. 2003, 125, 10782.
-
(a) Betley, T. A.; Peters, J, C. J. Am. Chem. Soc. 2003, 125, 10782.
-
-
-
-
34
-
-
84943077428
-
-
(b) Encmark, J. H.; Davis, B. R.; McGinncty, J. A.; Ibcrs, J. A. Chem. Commun. 1968, 96.
-
(1968)
Chem. Commun
, pp. 96
-
-
Encmark, J.H.1
Davis, B.R.2
McGinncty, J.A.3
Ibcrs, J.A.4
-
36
-
-
0013122721
-
-
(d) Bianchini, C.; Peruzzini, M.; Zanobini, F. Organometallics 1991, 10, 3415.
-
(1991)
Organometallics
, vol.10
, pp. 3415
-
-
Bianchini, C.1
Peruzzini, M.2
Zanobini, F.3
-
37
-
-
33845280913
-
-
(c) Bianchini, C.; Mealli, C.; Mcli, A.; Peruzzini, M.; Zanobini, F. J. Am. Chem. Soc. 1988, 110, 8725.
-
(1988)
J. Am. Chem. Soc
, vol.110
, pp. 8725
-
-
Bianchini, C.1
Mealli, C.2
Mcli, A.3
Peruzzini, M.4
Zanobini, F.5
-
38
-
-
0000089848
-
-
(f) Egan, J. W.; Haggerty, B. S.; Rheingold, A. L.; Sendlinger, S, C.; Theopold, K. H. J. Am. Chem. Soc. 1990, 112, 2445.
-
(1990)
J. Am. Chem. Soc
, vol.112
, pp. 2445
-
-
Egan, J.W.1
Haggerty, B.S.2
Rheingold, A.L.3
Sendlinger, S.C.4
Theopold, K.H.5
-
39
-
-
33746256415
-
-
(g) Fout, A. R.; Basuli, F.; Fan, H.; Tomaszewski, J.; Huffman, J. C.; Baik, M.-H.; Mindiola, D. J. Angew. Chem., Int. Ed. 2006, 45, 3291.
-
(2006)
Angew. Chem., Int. Ed
, vol.45
, pp. 3291
-
-
Fout, A.R.1
Basuli, F.2
Fan, H.3
Tomaszewski, J.4
Huffman, J.C.5
Baik, M.-H.6
Mindiola, D.J.7
-
40
-
-
0012397046
-
-
(a) Yamamoto, A.; Miura, Y.; Ito, T.; Chen, H. L.; Iri, K.; Ozawa, F.; Miki, K.; Sei, T.; Tanaka, N.; Kasai, N. Organometallics 1983, 2, 1429.
-
(1983)
Organometallics
, vol.2
, pp. 1429
-
-
Yamamoto, A.1
Miura, Y.2
Ito, T.3
Chen, H.L.4
Iri, K.5
Ozawa, F.6
Miki, K.7
Sei, T.8
Tanaka, N.9
Kasai, N.10
-
41
-
-
84982426532
-
-
(b) Hammer, R.; Klein, H.-F.; Schubert, U.; Frank, A.; Huttner, G. Angew. Chem., Int. Ed. Engl. 1976, 15, 612.
-
(1976)
Angew. Chem., Int. Ed. Engl
, vol.15
, pp. 612
-
-
Hammer, R.1
Klein, H.-F.2
Schubert, U.3
Frank, A.4
Huttner, G.5
-
42
-
-
37049104921
-
-
(c) Cecconi, F.; Ghilardi, C. A.; Midollini, S.; Moneti, S.; Orlandini, A.; Bacci, M. J. Chem. Soc, Chem. Commun. 1985, 731.
-
(1985)
J. Chem. Soc, Chem. Commun
, pp. 731
-
-
Cecconi, F.1
Ghilardi, C.A.2
Midollini, S.3
Moneti, S.4
Orlandini, A.5
Bacci, M.6
-
46
-
-
0000604488
-
-
Altomare, A.; Cascarano, G.; Giacovazzo, G.; Guagliardi, A.; Burla, M. C.; Polidori, G.; Camalli, M. J. Appt. Crystallogr. 1994, 27, 435.
-
(1994)
J. Appt. Crystallogr
, vol.27
, pp. 435
-
-
Altomare, A.1
Cascarano, G.2
Giacovazzo, G.3
Guagliardi, A.4
Burla, M.C.5
Polidori, G.6
Camalli, M.7
-
47
-
-
1242313195
-
-
Betteridgc, P. W.; Carruthers, J. R.; Cooper, R. I.; Prout, K.; Watkin, D, J. J. Appl. Crystallogr. 2003, 36, 1487.
-
(2003)
J. Appl. Crystallogr
, vol.36
, pp. 1487
-
-
Betteridgc, P.W.1
Carruthers, J.R.2
Cooper, R.I.3
Prout, K.4
Watkin, D.J.5
-
48
-
-
67649840409
-
-
Frisch, M. J. et al. Gaussian, Inc.; Wallingford, CT, 2004.
-
Frisch, M. J. et al. Gaussian, Inc.; Wallingford, CT, 2004.
-
-
-
-
52
-
-
50249098941
-
-
Roy, L. E.; Hay, P. J.; Martin, R. L. J. Chem. Theory Comput. 2008, 4, 1029-1031.
-
(2008)
J. Chem. Theory Comput
, vol.4
, pp. 1029-1031
-
-
Roy, L.E.1
Hay, P.J.2
Martin, R.L.3
-
53
-
-
43949164303
-
-
Ehlers, A. W.; Böhme, M.; Dapprich, S.; Gobbi, A.; Höllwarth, A.; Jonas, V.; Köhlcr, K. F.; Stcgmann, R.; Vcldkamp, A.; Frcnking, G. Chem. Phys. Lett. 1993, 208, 111-114.
-
(1993)
Chem. Phys. Lett
, vol.208
, pp. 111-114
-
-
Ehlers, A.W.1
Böhme, M.2
Dapprich, S.3
Gobbi, A.4
Höllwarth, A.5
Jonas, V.6
Köhlcr, K.F.7
Stcgmann, R.8
Vcldkamp, A.9
Frcnking, G.10
-
55
-
-
0001869943
-
-
Schaefer, H. F, Ed, Plenum; New York
-
Dunning, T. H.; Hay, P. J. In Modern Theoretical Chemistry; Schaefer, H. F., Ed.; Plenum; New York, 1976; Vol. 3, p 1-28.
-
(1976)
Modern Theoretical Chemistry
, vol.3
, pp. 1-28
-
-
Dunning, T.H.1
Hay, P.J.2
|