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Volumn 48, Issue 6, 2009, Pages 2349-2351

Zirconocene-iridium hydrido complexes: Arene carbon-hydrogen bond activation and formation of a planar square Zr2Ir2 complex

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EID: 64349101882     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic8020113     Document Type: Article
Times cited : (9)

References (39)
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    • Trost, B. M, Fleming, I, Paquette, L. A, Eds, Pergamon: Oxford, U.K
    • (a) Negishi, E. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Paquette, L. A., Eds.; Pergamon: Oxford, U.K., 1991; Vol. 5, pp 1163 - 1184.
    • (1991) Comprehensive Organic Synthesis , vol.5 , pp. 1163-1184
    • Negishi, E.1
  • 3
    • 8944222663 scopus 로고    scopus 로고
    • Conventional generation of divalent zirconocenes: (a) Manriquez, J. M.; McAister, D. R.; Sanner, R. D.; Bercaw, J. E. J. Am. Chem. Soc. 1978. 100, 2716-2724.
    • Conventional generation of divalent zirconocenes: (a) Manriquez, J. M.; McAister, D. R.; Sanner, R. D.; Bercaw, J. E. J. Am. Chem. Soc. 1978. 100, 2716-2724.
  • 7
    • 0011551341 scopus 로고    scopus 로고
    • Homometallic hydrides: (a) Weigold, H.; Bell, A. P.; Willing, R. I. J. Organomet. Chem. 1974, 73, C23-C24.
    • Homometallic hydrides: (a) Weigold, H.; Bell, A. P.; Willing, R. I. J. Organomet. Chem. 1974, 73, C23-C24.
  • 11
    • 0000844177 scopus 로고    scopus 로고
    • Heterometallic hydrides with main-group metals: (a) Marks, T. J.; Kolb. J. R. J. Am. Chem. Soc. 1975, 97, 3397-3401.
    • Heterometallic hydrides with main-group metals: (a) Marks, T. J.; Kolb. J. R. J. Am. Chem. Soc. 1975, 97, 3397-3401.
  • 15
    • 0001082904 scopus 로고    scopus 로고
    • ELHB hydrido complexes: (a) Bruno, J. W.; Huffman, J. C; Green. M. A.; Caulton, K. G. J. Am. Chem. Soc. 1984, 106, 8310-8312.
    • ELHB hydrido complexes: (a) Bruno, J. W.; Huffman, J. C; Green. M. A.; Caulton, K. G. J. Am. Chem. Soc. 1984, 106, 8310-8312.
  • 17
    • 0001730544 scopus 로고    scopus 로고
    • Bergman and co-workers have discussed the cooperative reactivity of ELHB hydrides having direct metal-metal bonds and clearly classified the cooperatively working systems and metailoligand bimetallics, a Baranger, A. M, Hollander, F. J, Bergman, R. G. J. Am. Chem. Soc. 1993, 115, 7890-7891
    • Bergman and co-workers have discussed the cooperative reactivity of ELHB hydrides having direct metal-metal bonds and clearly classified the cooperatively working systems and metailoligand bimetallics. (a) Baranger, A. M.; Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1993, 115, 7890-7891.
  • 22
    • 64349121151 scopus 로고    scopus 로고
    • 8) appeared to broaden at -80 °C (-13.99 ppm, W1/2 = 174.1 Hz), indicating the slower site exchange due to the fluxional nature.
    • 8) appeared to broaden at -80 °C (-13.99 ppm, W1/2 = 174.1 Hz), indicating the slower site exchange due to the fluxional nature.
  • 25
    • 64349098748 scopus 로고    scopus 로고
    • 3]ClO4.
    • 3]ClO4.
  • 27
    • 64349096253 scopus 로고    scopus 로고
    • Incontrast,hydrideligandeliminationofisolable(Cp2ZrH){Os(PMe2Ph)3, íí-H)3 leading to the unsaturated species is not reported. See ref 6
    • 3 leading to the unsaturated species is not reported. See ref 6.
  • 28
    • 64349093123 scopus 로고    scopus 로고
    • Longer alkyl groups on the silylene bridge of α«s· α-metallocenes can improve its solubility in hydrocarbon solvents. Bajgur, C. S, Tikkanen. W. R, Petersen, J. L. Inorg. Chem. 1985, 24, 2539-2546
    • Longer alkyl groups on the silylene bridge of α«s· α-metallocenes can improve its solubility in hydrocarbon solvents. Bajgur, C. S.; Tikkanen. W. R.; Petersen, J. L. Inorg. Chem. 1985, 24, 2539-2546.
  • 29
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    • 3 (6e).
    • 3 (6e).
  • 30
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    • 1H NMR.
    • 1H NMR.
  • 31
    • 0000125617 scopus 로고    scopus 로고
    • t·THF in mesitylene. Lee, S. Y.; Bergman. R. G. J. Am. Chem. Soc. 1995, 117, 5877-5878.
    • t·THF in mesitylene. Lee, S. Y.; Bergman. R. G. J. Am. Chem. Soc. 1995, 117, 5877-5878.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.