D 2-symmetric dirhodium catalyst derived from a 1,2,2-triarylcyclopropanecarboxylate ligand: Design, synthesis and application

Journal of the American Chemical Society

Volumn 133, Issue 47, 2011, Pages 19198-19204

  Qin, Changming ^a   Boyarskikh, Vyacheslav ^a   Hansen, Jørn H ^a   Hardcastle, Kenneth I ^a   Musaev, Djamaladdin G ^a   Davies, Huw M L ^a  

^a EMORY UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

C-H FUNCTIONALIZATION; CARBENOIDS; CHIRAL CATALYST; COMPUTATIONAL STUDIES; CYCLOPROPANATION; DIRHODIUM; ENANTIOSELECTIVE; ENANTIOSELECTIVE REACTIONS; ESTER GROUPS; TETRAKIS;

CHELATION; DICHLOROMETHANE; ENANTIOSELECTIVITY; LIGANDS; ORGANIC COMPOUNDS; RHODIUM;

CATALYSTS;

ACETIC ACID; CYCLOPROPANECARBOXYLIC ACID DERIVATIVE; DICHLOROMETHANE; DIRHODIUM TETRAKIS [1 (4 BROMOPHENYL) 2,2 DIPHENYLCYCLOPROPANECARBOXYLATE]; RHODIUM; STYRYLDIAZOACETATE; UNCLASSIFIED DRUG; BROMINATED HYDROCARBON; CYCLOPROPANE DERIVATIVE; LIGAND; ORGANOMETALLIC COMPOUND; TETRAKIS (R) (1 (4 BROMOPHENYL) 2,2 DIPHENYLCYCLOPROPANECARBOXYLATE); TETRAKIS-(R)-(1-(4-BROMOPHENYL)-2,2-DIPHENYLCYCLOPROPANECARBOXYLATE);

ARTICLE; CATALYST; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; CHIRALITY; COMPLEX FORMATION; COPE REARRANGEMENT; CRYSTAL STRUCTURE; CRYSTALLIZATION; CYCLOPROPANATION; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; STEREOCHEMISTRY; X RAY DIFFRACTION; CATALYSIS; CHEMISTRY; STEREOISOMERISM; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CATALYSIS; CRYSTALLOGRAPHY, X-RAY; CYCLOPROPANES; HYDROCARBONS, BROMINATED; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; RHODIUM; STEREOISOMERISM;

EID: 81855172116     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja2074104     Document Type: Article

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