Asymmetric Rh(II)-catalyzed cyclopropanation of alkenes with diacceptor diazo compounds: P -methoxyphenyl ketone as a general stereoselectivity controlling group

Journal of the American Chemical Society

Volumn 133, Issue 23, 2011, Pages 8972-8981

  Lindsay, Vincent N G ^a   Nicolas, Cyril ^a   Charette, André B ^a  

^a UNIVERSITÉ DE MONTRÉAL   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

AMINO ACID DERIVATIVES; CARBENES; CATALYTIC AMOUNTS; CYCLOPROPANATION; DIASTEREO- AND ENANTIOSELECTIVITY; DIAZO COMPOUNDS; ENANTIOPURE; LEWIS BASIS; MECHANISTIC STUDIES; STEREO-SELECTIVE;

AMINO ACIDS; CARBON DIOXIDE; CATALYSIS; ENANTIOSELECTIVITY; KETONES; OLEFINS; ORGANIC COMPOUNDS; PROPANE; RHODIUM; STEREOSELECTIVITY;

RHODIUM COMPOUNDS;

4 METHOXYPHENYL KETONE; ALKENE; AMINO ACID DERIVATIVE; CYCLOPROPANE ALPHA AMINO ACID; CYCLOPROPANE BETA AMINO ACID; KETONE DERIVATIVE; LEWIS BASE; RHODIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLOADDITION; CYCLOPROPANATION; DIASTEREOISOMER; ENANTIOSELECTIVITY; STEREOCHEMISTRY; STEREOSPECIFICITY;

ALKENES; AZIRIDINES; AZO COMPOUNDS; CATALYSIS; CYCLOPROPANES; KETONES; MODELS, MOLECULAR; MOLECULAR CONFORMATION; RHODIUM; STEREOISOMERISM; SUBSTRATE SPECIFICITY;

EID: 79958829858     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja201237j     Document Type: Article

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