The use of COP-OAc in the catalyst-controlled syntheses of 1,3-polyols

Synthesis

Volumn , Issue 22, 2011, Pages 3592-3603

  Kirsch, Stefan F ^a,b   Klahn, Philipp ^a,b   Menz, Helge ^a  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^b UNIVERSITY OF WUPPERTAL   (Germany)

Author keywords

catalysis; esters; natural products; palladium; polyols

Indexed keywords

CHAIN ELONGATION; ITERATIVE STRATEGY; NATURAL PRODUCTS; OLEFINATION; STEREOGENIC CENTERS; TOTAL SYNTHESIS;

ESTERIFICATION; ESTERS;

ALCOHOLS;

(3,6 DIHYDRO 6 OXO 2H PYRAN 2 YL)ACETALDEHYDE; 1,3 POLYOL DERIVATIVE; 1,5 BIS (TERT BUTYLDIMETHYLSILOXY)DODEC 2 ENE; 3 (TERT BUTYLDIMETHYLSILOXY)DEC 1 ENE; 3 (TERT BUTYLDIMETHYLSILOXY)DECANAL; 5 (TERT BUTYLDIMETHYLSILOXY)DODEC 1 EN 3 YL BENZOATE; 5 (TERT BUTYLDIMETHYLSILOXY)DODEC 2 EN 1 OL; 5 (TERT BUTYLDIMETHYLSILOXY)DODEC 2 ENYL 2,2,2 TRICHOLOACETIMIDATE; 5 (TERT BUTYLDIMETHYLSILOXY)PENT 1 EN 3 YL BENZOATE; 5 (TERT BUTYLDIMETHYLSILOXY)PENT 1 EN 3 YL BUT 3 ENOATE; 6 [2 (TERT BUTYLDIMETHYLSILOXY)ETHYL] 5,6 DIHYDRO 2H PYR AN 2 ONE; 6 HEPTYL 5,6 DIHYDROPYRAN 2 ONE; DEC 1 EN 3 YL BENZOATE; DEC 1 EN 3 YL BUT 3 ENOATE; DEC 2 EN 1 YL TRICHLOROACETIMIDATE; METHYL 5 (TERT BUTYLDIMETHYLSILOXY)DODEC 2 ENOATE; NATURAL PRODUCT; PALLADACYCLIC DERIVATIVE; PALLADIUM; POLYKETIDE; POLYOL; POLYRHACITIDE A; POLYRHACITIDE B; RUGULACTONE; UNCLASSIFIED DRUG;

ANDO OLEFINATION; ARTICLE; ASYMMETRIC CATALYSIS; CATALYST; CHEMICAL ANALYSIS; ESTERIFICATION; OLEFINATION; OVERMAN ESTERIFICATION; RING CLOSING METATHESIS; STEREOCHEMISTRY; SYNTHESIS;

EID: 80755135499     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0031-1289574     Document Type: Article

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