On the structure of passifloricin A: Asymmetric synthesis of the δ-lactones of (2Z,5S,7R,9S,11S)- and (2Z,5R,7R,9S,11S)-tetrahydroxyhexacos-2-enoic acid

Organic Letters

Volumn 5, Issue 9, 2003, Pages 1447-1449

  García Fortanet, Jorge ^a   Murga, Juan ^a   Carda, Miguel ^a   Marco, J Alberto ^b  

^a UNIVERSITAT JAUME I   (Spain)

^b UNIVERSITY OF VALENCIA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ACID; LACTONE; LACTONE DERIVATIVE; NATURAL PRODUCT; PASSIFLORICIN A; POLYKETIDE; TETRAHYDROXYHEXACOS 2 ENOIC ACID; UNCLASSIFIED DRUG; MONOUNSATURATED FATTY ACID; PYRONE DERIVATIVE;

ALLYLATION; ARTICLE; DRUG STRUCTURE; DRUG SYNTHESIS; EPIMER; METHODOLOGY; NUCLEAR MAGNETIC RESONANCE; RING CLOSING METATHESIS; STEREOCHEMISTRY; CHEMISTRY; CYCLIZATION; ESTERIFICATION; STEREOISOMERISM; SYNTHESIS;

CYCLIZATION; ESTERIFICATION; FATTY ACIDS, MONOUNSATURATED; LACTONES; PYRONES; STEREOISOMERISM;

EID: 0042766867     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol034182o     Document Type: Article

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33. (5S,7R,9R,11R)-Stereoisomer, found in another plant source, is also different from passifloricin A. Its structure has been confirmed by stereoselective synthesis: Nakata, T.; Suenaga, T.; Nakashima, K.; Oishi, T. Tetrahedron Lett. 1989, 30, 6529-6532.