Kinetic effects of increased proton transfer distance on proton-coupled oxidations of phenol-amines

Journal of the American Chemical Society

Volumn 133, Issue 43, 2011, Pages 17341-17352

  Markle, Todd F ^a,b   Rhile, Ian J ^a,c   Mayer, James M ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

^b UPPSALA UNIVERSITY   (Sweden)

^c ALBRIGHT COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMINO-PHENOLS; ANHARMONIC; COMPUTATIONAL ANALYSIS; COMPUTATIONAL STUDIES; DFT CALCULATION; DONOR-ACCEPTOR DISTANCE; DRIVING FORCES; HYDROGEN BONDED SYSTEMS; KINETIC EFFECT; KINETIC ISOTOPE EFFECTS; KINETIC MODELS; KINETIC STUDY; ORDERS OF MAGNITUDE; PROTON-COUPLED ELECTRON TRANSFER; RADICAL CATIONS; TRANSFER REACTION; TUNNELING MODELS; VIBRATIONAL EXCITED STATE;

AMINES; BROMINE COMPOUNDS; ELECTRON TRANSITIONS; FREE RADICAL REACTIONS; ISOTOPES; KINETIC THEORY; KINETICS; OXIDATION; PHENOLS; POSITIVE IONS; QUANTUM CHEMISTRY; RATE CONSTANTS; SPHERES; X RAY CRYSTALLOGRAPHY;

PROTONS;

1 AMINO 4,6 DI TERT BUTYL 7 HYDROXYINDAN; 2,4 DI TERT BUTYL 6 (DIPHENYLAMINOMETHYL)PHENOL; AMINE; PHENOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONCERTED PROTON ELECTRON TRANSFER; KINETIC ISOTOPE EFFECT; KINETICS; OXIDATION; PROTON COUPLED ELECTRON TRANSFER; PROTON TRANSPORT; X RAY CRYSTALLOGRAPHY;

AMINES; KINETICS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PHENOLS; PROTONS; STEREOISOMERISM; THERMODYNAMICS;

EID: 80054993941     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja2056853     Document Type: Article

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