Iron(II) chloride catalyzed alkylation of propargyl ethers: Direct functionalization of an sp3 C-H bond adjacent to oxygen

Synthesis

Volumn , Issue 17, 2011, Pages 2803-2809

  Xie, Yongju ^a   Yu, Ming ^a   Zhang, Yuhong ^a,b  

^a ZHEJIANG UNIVERSITY   (China)

^b LANZHOU UNIVERSITY   (China)

Author keywords

alkylation; C C bond formation; C H functionalization; iron catalyzed; propargyl ether

Indexed keywords

2 ,3-DICHLORO-5 ,6-DICYANO-1 ,4-BENZOQUINONE; C-C BOND FORMATION; C-H BOND; C-H FUNCTIONALIZATION; DIRECT ALKYLATION; FUNCTIONALIZATIONS; IRON CHLORIDES; IRON-CATALYZED; MILD REACTION CONDITIONS; PROPARGYL ETHERS;

ALKYLATION; CATALYSIS; CHLORINE COMPOUNDS; IRON; IRON COMPOUNDS; KETONES; ORGANIC COMPOUNDS; OXYGEN;

ETHERS;

1,3 DIKETONE; 1,5 BIS(4 BROMOPHENYL) 2 (METHOXYMETHYL)PENT 2 EN 4 YN 1 ONE; 1,5 BIS(4 CHLOROPHENYL) 2 (METHOXYMETHYL)PENT 2 EN 4 YN 1 ONE; 1,5 BIS(4 FLUOROPHENYL) 2 (METHOXYMETHYL)PENT 2 EN 4 YN 1 ONE; 2 (METHOXYMETHYL) 1,5 DI 1,2 PHENYLPENT 2 EN 4 YN 1 ONE; 2 (METHOXYMETHYL) 1,5 DI 1,3 PHENYLPENT 2 EN 4 YN 1 ONE; 2 (METHOXYMETHYL) 1,5 DI 1,4 PHENYLPENT 2 EN 4 YN 1 ONE; 2 (METHOXYMETHYL) 1,5 PHENYLPENT 2 EN 4 YN 1 ONE; 2 ACETYL 2 (1 METHOXY 3 1,2 TOLYLPROP 2 YNYL)CYCLOPENTANONE; 2 ACETYL 2 (1 METHOXY 3 PHENYLPROP 2 YNYL)CYCLOEHEXANONE; 2 ACETYL 2 (1 METHOXY 3 PHENYLPROP 2 YNYL)CYCLOPENTANONE; 2,3 DICHLORO 5,6 DICYANO 1,4 BENZOQUINONE; 3 (1 ALLYLOXY 3 PHENYLPROP 2 YNYL) 3 METHYLPENTANE 2,4 DIONE; 3 (1 METHOXY 3 1,2 TOLYLPROP 2 YNYL) 3 METHYLPENTANE 2,4 DIONE; 3 (1 METHOXY 3 1,3 TOLYLPROP 2 YNYL) 3 METHYLPENTANE 2,4 DIONE; 3 (1 METHOXY 3 1,4 TOLYLPROP 2 YNYL) 3 METHYLPENTANE 2,4 DIONE; 3 (1 METHOXY 3 PHENYLPROP 2 YNYL) 3 METHYLPENTANE 2,4 DIONE; 3 (1 METHOXY 3 THIOPHEN 2 YLPROP 2 YNYL) 3 METHYLPENTANE 2,4 DIONE; 3 [1 (BENZYLOXY) 3 PHENYLPROP 2 YNYL] 3 METHYLPENTANE 2,4 DIONE; 3 [1 METHOXY 3 (METHOXYPHENYL)PROP 2 YNYL] 3 METHYLPENTANE 2,4 DIONE; 3 [3 (2 BROMOPHENYL) 1 METHOXYPROP 2 YNYL] 3 METHYLPENTANE 2,4 DIONE; 3 [3 (4 BROMOPHENYL) 1 METHOXYPROP 2 YNYL] 3 METHYLPENTANE 2,4 DIONE; 3 [3 (4 CHLOROPHENYL) 1 METHOXYPROP 2 YNYL] 3 METHYLPENTANE 2,4 DIONE; 3 [3 (4 FLUOROPHENYL) 1 METHOXYPROP 2 YNYL] 3 METHYLPENTANE 2,4 DIONE; ETHER DERIVATIVE; FERROUS CHLORIDE; OXYGEN; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; OXIDATION;

EID: 80052072474     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0030-1260131     Document Type: Article

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