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(a) Li, Z.; Bohle, D. S.; Li, C.-J. Proc. Natl. Acad. Sci. U.S.A. 2006, 103, 8928.
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(b) Zhang, Y.; Li, C.-J. Angew. Chem., Int. Ed. 2006, 45, 1949.
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(c) Wan, X.; Xing, D.; Fang, Z.; Li, B.; Zhao, F.; Zhang, K.; Yang, L.; Shi, Z. J. Am. Chem. Soc. 2006, 128, 12046.
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(d) Marayama, T.; Suga, S.; Yoshida, J.-I. J. Am. Chem. Soc. 2005, 127, 7324.
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(e) DeBoef, B.; Pastine, S. J.; Sames, D. J. Am. Chem. Soc. 2004, 126, 6556.
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DDQ-mediated C-H bond activation was reported: Zhang, Y.; Li, C.-J. J. Am. Chem. Soc. 2006, 128, 4242.
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DDQ-mediated C-H bond activation was reported: Zhang, Y.; Li, C.-J. J. Am. Chem. Soc. 2006, 128, 4242.
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21
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12344302489
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An alternative method for generation of the thionium precursor, hemithioacetal. is based on the addition of thiols to glyoxamide; see: McAllister, L. A, McCormick, R. A, Brand, S, Procter, D. J. Angew. Chem, Int. Ed. 2005, 44, 452
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An alternative method for generation of the thionium precursor, hemithioacetal. is based on the addition of thiols to glyoxamide; see: McAllister, L. A.; McCormick, R. A.; Brand, S.; Procter, D. J. Angew. Chem., Int. Ed. 2005, 44, 452.
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22
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58149198179
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No desired product was obtained when p-fluoranil, p-chloranil. and p-bromanil were used as oxidants under the same reaction conditions
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No desired product was obtained when p-fluoranil, p-chloranil. and p-bromanil were used as oxidants under the same reaction conditions.
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23
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58149193827
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One of possibilities of C H bond oxidation is initiated by single electron transfer from sulfur to quinone; see: Gorner. H. Pholochem. Photobiol. 2006, 82, 71
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One of possibilities of C H bond oxidation is initiated by single electron transfer from sulfur to quinone; see: Gorner. H. Pholochem. Photobiol. 2006, 82, 71.
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This step is reversible. Compound 3e was obtained as a major product by the reaction of 3d and 2b. Oxidative cleavage benzylic C-C bonds assisted by heteroatoms: Wang, L, Seiders, J. R, II; Floreancig, P. E. J. Am. Chem. Soc. 2004, 126. 12596
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This step is reversible. Compound 3e was obtained as a major product by the reaction of 3d and 2b. Oxidative cleavage benzylic C-C bonds assisted by heteroatoms: Wang, L.; Seiders, J. R., II; Floreancig, P. E. J. Am. Chem. Soc. 2004, 126. 12596.
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25
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33646900271
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Compound 3a was transformed into 4b in 93% isolated yield at 100°C for 8 h in the presence of 2 equiv of o-chloranil. For related examples of C-S bond cleavage, see: (a) Baciocchi, E.; Del, Giacco, T.; Giombolini, P.; Lanzalunga, O. Tetrahedron 2006, 62, 6566.
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Compound 3a was transformed into 4b in 93% isolated yield at 100°C for 8 h in the presence of 2 equiv of o-chloranil. For related examples of C-S bond cleavage, see: (a) Baciocchi, E.; Del, Giacco, T.; Giombolini, P.; Lanzalunga, O. Tetrahedron 2006, 62, 6566.
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(b) Mukaiyama, T.; Narasaka, K.; Hokonok, H. J. Am. Chem. Soc. 1969, 91, 4315.
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