Aryl C-H amination by diruthenium nitrides in the solid state and in solution at room temperature: Experimental and computational study of the reaction mechanism

Journal of the American Chemical Society

Volumn 133, Issue 33, 2011, Pages 13138-13150

  Long, Amanda Kae Musch ^a   Timmer, George H ^a   Pap, József S ^a,b   Snyder, Jamie Lynn ^a   Yu, Renyuan Pony ^a   Berry, John F ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b UNIVERSITY OF PANNONIA   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

ARRHENIUS; ARYL RINGS; C-H BOND; C-H FUNCTIONALIZATION; C-H INSERTION; COMPUTATIONAL STUDIES; DIFFERENTIAL SCANNING CALORIMETRIC MEASUREMENTS; DIRUTHENIUM; ELECTROPHILIC AROMATIC SUBSTITUTIONS; FORMAMIDINATE; INTRAMOLECULAR ATTACK; KINETIC DATA; NITROGEN ATOM; REACTION MECHANISM; REACTION PATHWAYS; ROOM TEMPERATURE; THERMAL GRAVIMETRIC ANALYSIS;

CHLORINE; GRAVIMETRIC ANALYSIS; NITRIDES; PHOTOLYSIS; REACTION INTERMEDIATES; RUTHENIUM COMPOUNDS; THERMOGRAVIMETRIC ANALYSIS;

CHLORINE COMPOUNDS;

CARBON; DICHLOROMETHANE; DIRUTHENIUM NITRIDE; HYDROGEN; LIGAND; NITROGEN; RUTHENIUM COMPLEX; RUTHENIUM DERIVATIVE; UNCLASSIFIED DRUG;

AMINATION; ARTICLE; ATOM; BIOTRANSFORMATION; CHEMICAL BOND; CHEMICAL REACTION; COMPLEX FORMATION; CONTROLLED STUDY; DENSITY FUNCTIONAL THEORY; DIFFERENTIAL SCANNING CALORIMETRY; ELECTROPHILICITY; FREEZE THAWING; KINETICS; MOLECULAR DYNAMICS; PHOTOLYSIS; RING OPENING; ROOM TEMPERATURE; SOLID STATE; SOLUTION AND SOLUBILITY; SUBSTITUTION REACTION; THERMAL ANALYSIS; THERMODYNAMICS; THERMOGRAVIMETRY; THERMOLYSIS;

EID: 80051722296     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja203993p     Document Type: Article

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