Aryl C-H bond amination by an electrophilic diruthenium nitride

Journal of the American Chemical Society

Volumn 132, Issue 35, 2010, Pages 12228-12230

  Musch Long, Amanda Kae ^a   Yu, Renyuan Pony ^a   Timmer, George H ^a   Berry, John F ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

C-H BOND; DENSITY FUNCTIONAL THEORY CALCULATIONS; DIRUTHENIUM; FORMAMIDINATE; TWO-STEP REACTIONS;

DENSITY FUNCTIONAL THEORY; DIFFERENTIAL SCANNING CALORIMETRY; NITRIDES; RUTHENIUM COMPOUNDS;

THERMOGRAVIMETRIC ANALYSIS;

AROMATIC COMPOUND; CARBON; DIRUTHENIUM NITRIDE; HYDROGEN; INORGANIC COMPOUND; LIGAND; UNCLASSIFIED DRUG;

AMINATION; ARTICLE; ATOM; CHEMICAL REACTION; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; DIFFERENTIAL SCANNING CALORIMETRY; ELECTRON SPIN RESONANCE; ELECTROPHILICITY; HYDROGEN BOND; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; THERMOGRAVIMETRY;

AMINATION; COORDINATION COMPLEXES; CRYSTALLOGRAPHY, X-RAY; MODELS, MOLECULAR; MOLECULAR DYNAMICS SIMULATION; NITROGEN COMPOUNDS; ORGANOMETALLIC COMPOUNDS; RUTHENIUM; TEMPERATURE;

EID: 77956243392     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1062955     Document Type: Article

References (21)

1. Davies, H. M. L. and Manning, J. R. Nature 2008, 451, 417-424
2. Espino, C. G. and Du Bois, J. Rhodium(II)-Catalyzed Oxidative Amination. In Modern Rhodium-Catalyzed Organic Reactions; Evans, P. A., Ed.; Wiley-VCH: Weinheim, 2005.
3. Pap, J. S., DeBeer, S., and Berry, J. F. Angew. Chem., Int. Ed. 2008, 47, 10102-10105
4. Schöffel, J., Rogachev, A. Y., DeBeer, S., and Burger, P. Angew. Chem., Int. Ed. 2009, 48, 4734-4738
5. Lin, C., Protasiewicz, J. D., and Ren, T. Inorg. Chem. 1996, 35, 7455-7458
6. Chen, W.-Z., De Silva, V., Lin, C., Abellard, J., Marcus, D. M., and Ren, T. J. Cluster Sci. 2005, 16, 151-165
7. Cotton, F. A. and Ren, T. Inorg. Chem. 1991, 30, 3675-3679
8. Lin, C., Ren, T., Valente, E. J., Zubkowski, J. D., and Smith, E. T. Chem. Lett. 1997, 753-754
9. Fryhle, C. B. and Solomons, T. W. G. Organic Chemistry, 9th ed.; John Wiley: Danvers, MA, 2008; pp 651 652.
10. Berry, J. F. Comments Inorg. Chem. 2009, 30, 28-66
11. Silvia, J. S. and Cummins, C. C. J. Am. Chem. Soc. 2009, 131, 446-447
12. Eikey, R. A. and Abu-Omar, M. M. Coord. Chem. Rev. 2003, 243, 83-124
13. Scepaniak, J. J., Fulton, M. D., Bontchev, R. P., Duesler, E. N., Kirk, M. L., and Smith, J. L. J. Am. Chem. Soc. 2008, 130, 10515-10517
14. Schröder, D. and Schwarz, H. Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 18114-18119
15. Schlangen, M., Neugebauer, J., Reiher, M., Schröder, D., Loěpez, J. P., Haryono, M., Heinemann, F. W., Grohmann, A., and Schwarz, H. J. Am. Chem. Soc. 2008, 130, 4285-4294
16. Buschhorn, D., Pink, M., Fan, H., and Caulton, K. G. Inorg. Chem. 2008, 47, 5129-5135
17. Crevier, T. J., Bennett, B. K., Soper, J. D., Bowman, J. A., Dehestani, A., Hrovat, D. A., Lovell, S., Kaminsky, W., and Mayer, J. M. J. Am. Chem. Soc. 2001, 123, 1059-1071
18. Man, W.-L., Tang, T.-M., Wong, T.-W., Lau, T.-C., Peng, S.-M., and Wong, W.-T. J. Am. Chem. Soc. 2004, 126, 478-479
19. Insertion of a putative nickel nitrido group into aliphatic C-H bonds has been proposed. See: Hennig, H., Hofbauer, K., Handke, K., and Stich, R. Angew. Chem., Int. Ed. Engl. 1997, 36, 408-410
20. Lin, C., Ren, T., Valente, E. J., and Zubkowski, J. D. J. Organomet. Chem. 1999, 579, 114-121
21. Cotton, F. A., Murillo, C. A., and Walton, R. A. Multiple Bonds Between Metal Atoms, 3rd ed.; Springer: New York, NY, 2005; pp 381 382.