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Volumn 48, Issue 26, 2009, Pages 4734-4738

Isolation and hydrogenation of a complex with a terminal iridium-nitrido bond

Author keywords

Hydrogenation; Iridium; Multiple bonds; Nitrides; Quantum chemistry

Indexed keywords

AMIDO COMPLEXES; MULTIPLE BONDS; TRANSITION-METAL COMPLEX; X RAY CRYSTAL STRUCTURES;

EID: 70349975610     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200901494     Document Type: Article
Times cited : (107)

References (32)
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    • note
    • Details of the syntheses and characterization, thermo- and physicochemical measurements, and further information on the quantum chemical calculations, including the geometry-optimized structures, characterization of the stationary points, and employed program packages, are described in the Supporting Information
  • 21
    • 8644225597 scopus 로고    scopus 로고
    • 15NNMR shift of O = 1154.2 ppm at the DFT level of theory for complex 1-H is in accordance with this value (for details see the Supporting Information). A similar good agreement of experimental and calculated data for nitrido complexes was reported: E. L. Sceats, J. S. Figueroa, C. C. Cummins, N. M. Loening, P. Van der Wel, R. G. Griffin, Polyhedron 2004,25,2751-2768.
    • (2004) Polyhedron , vol.25 , pp. 2751-2768
    • Sceats, E.L.1    Figueroa, J.S.2    Cummins, C.C.3    Loening, N.M.4    Van Der Wel, P.5    Griffin, R.G.6
  • 23
    • 70349955588 scopus 로고    scopus 로고
    • 3. CCDC 713135 (1), 713139 (2), 713136 (3), 713137 (4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data- request/cif.
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  • 29
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    • 4, which was introduced for electron bookkeeping in metal nitrosyl complexes and also applied by Wieghardt's group for transitionmetal nitrido compounds
    • (2008) Organometallics , vol.27 , pp. 2699-2705
    • Zhu, D.1    Budzelaar, P.H.M.2
  • 32
    • 70349938661 scopus 로고    scopus 로고
    • note
    • n+1(r) is the electron density at the same geometry with n + 1 electrons.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.