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A dirhodium complex with an axial N-heterocyclic carbene ligand has been described (J. P. Snyder, A. Padwa, T. Stengel, A. J. Arduengo III, A. Jockisch, H.-J. Kim, J. Am. Chem. Soc. 2001, 123, 11318), though it was determined that the Rh-C bond did not have significant multiple bond character.
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A dirhodium complex with an axial N-heterocyclic carbene ligand has been described (J. P. Snyder, A. Padwa, T. Stengel, A. J. Arduengo III, A. Jockisch, H.-J. Kim, J. Am. Chem. Soc. 2001, 123, 11318), though it was determined that the Rh-C bond did not have significant multiple bond character.
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57749105358
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See the Supporting Information for further details
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See the Supporting Information for further details.
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17644421785
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IV-nitrido complex is also known but this species has a short (1.63 Å) Ru≡N bond, see: A. Walstrom, M. Pink, X. Yang, J. Tomaszewski, M.-H. Baik, K. G. Caulton, J. Am. Chem. Soc. 2005, 127, 5330.
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IV-nitrido complex is also known but this species has a short (1.63 Å) Ru≡N bond, see: A. Walstrom, M. Pink, X. Yang, J. Tomaszewski, M.-H. Baik, K. G. Caulton, J. Am. Chem. Soc. 2005, 127, 5330.
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