SmI2-mediated radical cross-couplings of α-hydroxylated aza-hemiacetals and N, S -acetals with α,β-unsaturated compounds: Asymmetric synthesis of (+)-hyacinthacine A2, (-)-uniflorine A, and (+)-7- epi -casuarine

Journal of Organic Chemistry

Volumn 76, Issue 12, 2011, Pages 4952-4963

  Liu, Xue Kui ^a,b   Qiu, Shi ^a   Xiang, Yong Gang ^a   Ruan, Yuan Ping ^a   Zheng, Xiao ^a,b   Huang, Pei Qiang ^a  

^a Institute of Biomedical Materials and Engineering   (China)

^b XIAMEN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC SYNTHESIS; CONTROLLED EXPERIMENT; COUPLING REACTION; CROSS-COUPLINGS; MEDIATED REACTIONS; N ,S-ACETALS; PYRROLIDINES; RADICAL COUPLING REACTIONS; RADICAL MECHANISM; SWITCHABLE;

CARBONYL COMPOUNDS; CARBONYLATION; HYDROXYLATION;

UNSATURATED COMPOUNDS;

7 EPI CASUARINE; ACETAL; ALKALOID; CARBONYL DERIVATIVE; HETEROCYCLIC COMPOUND; HYACINTHACINE A2; PIPERIDINE DERIVATIVE; PYRROLIDINE DERIVATIVE; SAMARIUM; SAMARIUM IODIDE; UNCLASSIFIED DRUG; UNIFLORINE A; ACETAL DERIVATIVE; CASUARINE; FREE RADICAL; INDOLIZINE DERIVATIVE; IODIDE; PYRROLE DERIVATIVE; PYRROLIZIDINE ALKALOID; SAMARIUM DIIODIDE;

ARTICLE; ASYMMETRIC SYNTHESIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CROSS COUPLING REACTION; DIASTEREOISOMER; HYDROXYLATION; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ACETALS; ALKALOIDS; AZA COMPOUNDS; FREE RADICALS; HYDROXYLATION; INDOLIZINES; IODIDES; MOLECULAR STRUCTURE; PYRROLES; PYRROLIZIDINE ALKALOIDS; SAMARIUM; STEREOISOMERISM;

EID: 79958847766     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo200600n     Document Type: Article

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