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Volumn 29, Issue 17, 2010, Pages 3966-3972

A versatile cuprous synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene)

Author keywords

[No Author keywords available]

Indexed keywords

IMIDAZOL-2-YLIDENE; SI-C BOND; SYNTHONS; X-H BOND;

EID: 77956410236     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100733n     Document Type: Article
Times cited : (112)

References (81)
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    • Complex 2 was recently shown to be active in C-H bond functionalization reactions, manuscript submitted.
    • Complex 2 was recently shown to be active in C-H bond functionalization reactions: Boogeart, I. F. F.; Fortman, G. C.; Furst, M.R. L.; Cazin, C. S. J; Nolan, S. P., manuscript submitted.
    • Boogeart, I.F.F.1    Fortman, G.C.2    Furst, M.R.L.3    Cazin, C.S.J.4    Nolan, S.P.5
  • 35
    • 77956402921 scopus 로고    scopus 로고
    • Unlike its gold congener (10) synthetic attempts using NaOH and KOH proved unsuccessful, yet once isolated, solid-state samples of 2 left in the air for more than 1 month showed no visible decomposition as monitored by NMR spectroscopy.
    • Unlike its gold congener (10) synthetic attempts using NaOH and KOH proved unsuccessful, yet once isolated, solid-state samples of 2 left in the air for more than 1 month showed no visible decomposition as monitored by NMR spectroscopy.
  • 38
    • 77954271854 scopus 로고    scopus 로고
    • a of 2 is suspected as a result of the the higher electronegativity of Cu(I) compared to Au(I). This greater electronegativity would decrease the electron density about the oxygen atom and thus lower its nucleophilicity.
    • a of 2 is suspected as a result of the the higher electronegativity of Cu(I) compared to Au(I). This greater electronegativity would decrease the electron density about the oxygen atom and thus lower its nucleophilicity.
    • (2010) J. Am. Chem. Soc. , vol.132 , pp. 8858-8859
    • Boogaerts, I.I.F.1    Slawin, A.M.Z.2    Nolan, S.P.3
  • 48
    • 77956402418 scopus 로고    scopus 로고
    • See Supporting Information for details. X-ray diffraction data for this complex can be found in the SI.
    • See Supporting Information for details. X-ray diffraction data for this complex can be found in the SI.
  • 56
    • 85042547097 scopus 로고    scopus 로고
    • Luo Y.-R. Ed.; CRC Press: Boca Raton, FL,; and 255.
    • Comprehensive Handbook of Chemical Bond Energies; Luo, Y.-R., Ed.; CRC Press: Boca Raton, FL, 2007; 462 and 255.
    • (2007) Comprehensive Handbook of Chemical Bond Energies , pp. 462
  • 66
    • 77956404733 scopus 로고    scopus 로고
    • 1H NMR spectroscopy.
    • 1H NMR spectroscopy.
  • 68
    • 36849065859 scopus 로고    scopus 로고
    • For a monograph on NHC in synthesis see:;, Ed.; Wiley-VCH: Weinheim.
    • For a monograph on NHC in synthesis see: N-Heterocyclic Carbenes in Synthesis; Nolan, S. P., Ed.; Wiley-VCH: Weinheim, 2006.
    • (2006) N-Heterocyclic Carbenes in Synthesis
    • Nolan, S.P.1
  • 69
    • 84908659806 scopus 로고    scopus 로고
    • For a review on NHC in late transition metal catalysis see
    • For a review on NHC in late transition metal catalysis see: Díez-González, S.; Marion, N.; Nolan, S. P. Chem. Rev. 2009, 109, 3612
    • (2009) Chem. Rev. , vol.109 , pp. 3612
    • Díez-González, S.1    Marion, N.2    Nolan, S.P.3
  • 74
    • 34547659129 scopus 로고    scopus 로고
    • Hetero-bimetallic complexes have led to some interesting chemistry; see for example
    • Hetero-bimetallic complexes have led to some interesting chemistry; see for example: Ruiz, J.; Perandones, B. F. J. Am. Chem. Soc. 2007, 129, 9298
    • (2007) J. Am. Chem. Soc. , vol.129 , pp. 9298
    • Ruiz, J.1    Perandones, B.F.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.