Au(I)-catalyzed efficient synthesis of functionalized bicyclo[3.2.0] heptanes

Journal of the American Chemical Society

Volumn 130, Issue 22, 2008, Pages 6944-6945

  Li, Guotao ^a   Huang, Xiaogen ^a   Zhang, Liming ^a  

^a UNIVERSITY OF NEVADA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BICYCLO[3.2.0]HEPTANE DERIVATIVE; GOLD;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CYCLIZATION; CYCLOADDITION; REACTION ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ALKYNES; BICYCLO COMPOUNDS; CATALYSIS; CYCLOPROPANES; ETHYL ETHERS; GOLD; HEPTANES; KETONES; SILICON DIOXIDE;

EID: 44449159964     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja802294t     Document Type: Article

References (25)

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23. 2 at room temperature. However, slow decomposition was observed at 80°C.
24. 1H NMR gave a ratio of 5/1 for the two compounds and a combined yield of more than 90%.
25. 2 did not stay catalytically active in the reaction after 15 to 30 min.