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Volumn 26, Issue 19, 2007, Pages 4704-4707

Synthesis and reactivity of air-stable N-heterocyclic carbene gold(I) bis(trifluoromethanesulfonyl)imidate complexes

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; COORDINATION REACTIONS; GOLD COMPOUNDS; METAL COMPLEXES; REACTION RATES; SYNTHESIS (CHEMICAL);

EID: 34748850041     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om7006002     Document Type: Article
Times cited : (212)

References (39)
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    • For recent reviews on gold catalysis, see: a
    • For recent reviews on gold catalysis, see: (a) Gorin, D. J.; Toste, F. D. Nature 2007, 46, 395-403.
    • (2007) Nature , vol.46 , pp. 395-403
    • Gorin, D.J.1    Toste, F.D.2
  • 3
    • 33845546747 scopus 로고    scopus 로고
    • For selected recent examples of gold(I)-catalyzed reactions, see
    • (c) Hashmi, S. A.; Huchings, G. J. Angew. Chem., Int. Ed. 2006,45, 7896-7936. For selected recent examples of gold(I)-catalyzed reactions, see:
    • (2006) Angew. Chem., Int. Ed , vol.45 , pp. 7896-7936
    • Hashmi, S.A.1    Huchings, G.J.2
  • 10
    • 33748792796 scopus 로고    scopus 로고
    • López, S.: Herrero-Gómez, E.; PérezGalán, P.; Nieto-Oberhuber, C.; Echavarren. A. M. Angew. Chem., Int. Ed. 2006, 44, 6029-6032.
    • (j) López, S.: Herrero-Gómez, E.; PérezGalán, P.; Nieto-Oberhuber, C.; Echavarren. A. M. Angew. Chem., Int. Ed. 2006, 44, 6029-6032.
  • 12
    • 34748865796 scopus 로고    scopus 로고
    • Protonation of an alkylgold(I) complex with a strong acid may also be used to generate the cationic species; however, these conditions are not always compatible with the substrates
    • Protonation of an alkylgold(I) complex with a strong acid may also be used to generate the cationic species; however, these conditions are not always compatible with the substrates.
  • 13
    • 34748903269 scopus 로고    scopus 로고
    • The use of a glovebox is required to properly weigh the silver salt
    • The use of a glovebox is required to properly weigh the silver salt.
  • 14
    • 34748846673 scopus 로고    scopus 로고
    • -), and the free Lewis acid MF., can act as an oxidizing agent and thus cause unwanted side reactions. See: (a) Raabe, I.; Krossing, I. Angew. Chem., Int. Ed. 2004, 43, 20662090.
    • -), and the free Lewis acid MF., can act as an oxidizing agent and thus cause unwanted side reactions. See: (a) Raabe, I.; Krossing, I. Angew. Chem., Int. Ed. 2004, 43, 20662090.
  • 16
    • 25844453872 scopus 로고    scopus 로고
    • 6 as active catalysts for cycloisomerization. See: (a) Nieto-Oberhuber, C.; López, S.; Muñoz, M. P.; Cardenas, D. J.; Bunuel, E.; Nevado, C.; Echavarren, A. M. Angew. Chem., Int. Ed. 2005, 44. 6146-6148.
    • 6 as active catalysts for cycloisomerization. See: (a) Nieto-Oberhuber, C.; López, S.; Muñoz, M. P.; Cardenas, D. J.; Bunuel, E.; Nevado, C.; Echavarren, A. M. Angew. Chem., Int. Ed. 2005, 44. 6146-6148.
  • 35
    • 24044524181 scopus 로고    scopus 로고
    • Fructos, M. R.; Belderrain, T. R.; de Fremont, P.; Scott, N. M.; Nolan, S. P.; Diaz-Requejo, M. M.; Perez, P. J. Angew. Chem., Int. Ed. 2005. 44, 5284-5288. See also ref le.
    • (d) Fructos, M. R.; Belderrain, T. R.; de Fremont, P.; Scott, N. M.; Nolan, S. P.; Diaz-Requejo, M. M.; Perez, P. J. Angew. Chem., Int. Ed. 2005. 44, 5284-5288. See also ref le.
  • 37
    • 34447320531 scopus 로고    scopus 로고
    • 2 complex in the gold-catalyzed intramolecular redox reaction of sulfinylalkynes: Li, G.; Zhang, L. Angew. Chem., Int. Ed. 2007, 46, 5156-5159. However, the authors did not give information about the synthesis and isolation of this complex.
    • 2 complex in the gold-catalyzed intramolecular redox reaction of sulfinylalkynes: Li, G.; Zhang, L. Angew. Chem., Int. Ed. 2007, 46, 5156-5159. However, the authors did not give information about the synthesis and isolation of this complex.
  • 39
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    • See the Supporting Information
    • See the Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.