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Protonation of an alkylgold(I) complex with a strong acid may also be used to generate the cationic species; however, these conditions are not always compatible with the substrates
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Protonation of an alkylgold(I) complex with a strong acid may also be used to generate the cationic species; however, these conditions are not always compatible with the substrates.
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13
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34748903269
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The use of a glovebox is required to properly weigh the silver salt
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The use of a glovebox is required to properly weigh the silver salt.
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14
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34748846673
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-), and the free Lewis acid MF., can act as an oxidizing agent and thus cause unwanted side reactions. See: (a) Raabe, I.; Krossing, I. Angew. Chem., Int. Ed. 2004, 43, 20662090.
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-), and the free Lewis acid MF., can act as an oxidizing agent and thus cause unwanted side reactions. See: (a) Raabe, I.; Krossing, I. Angew. Chem., Int. Ed. 2004, 43, 20662090.
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16
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25844453872
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6 as active catalysts for cycloisomerization. See: (a) Nieto-Oberhuber, C.; López, S.; Muñoz, M. P.; Cardenas, D. J.; Bunuel, E.; Nevado, C.; Echavarren, A. M. Angew. Chem., Int. Ed. 2005, 44. 6146-6148.
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6 as active catalysts for cycloisomerization. See: (a) Nieto-Oberhuber, C.; López, S.; Muñoz, M. P.; Cardenas, D. J.; Bunuel, E.; Nevado, C.; Echavarren, A. M. Angew. Chem., Int. Ed. 2005, 44. 6146-6148.
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2 complex in the gold-catalyzed intramolecular redox reaction of sulfinylalkynes: Li, G.; Zhang, L. Angew. Chem., Int. Ed. 2007, 46, 5156-5159. However, the authors did not give information about the synthesis and isolation of this complex.
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See the Supporting Information
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See the Supporting Information.
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