Cu(NO3)2·3H2O-mediated synthesis of 4′-(2-pyridyl)-2,2′:6′,2″-terpyridine (L2) from N-(2-pyridylmethyl)pyridine-2-methylketimine (L1). A C-C bond-forming reaction and the structure of {[Cu(L2)(OH)(NO3)][Cu(L2)(NO3) 2]}·2H2O

Inorganic Chemistry

Volumn 45, Issue 20, 2006, Pages 7994-7996

  Padhi, Sumanta Kumar ^a   Manivannan, Vadivelu ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY GUWAHATI   (India)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER; COPPER(II) NITRATE; NITRATE; ORGANOMETALLIC COMPOUND; PYRIDINE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

COPPER; CRYSTALLOGRAPHY, X-RAY; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; NITRATES; ORGANOMETALLIC COMPOUNDS; PYRIDINES;

EID: 33750352535     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic060968h     Document Type: Article

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19. -1): 1637, 1590, 1463, 1434.
20. iso = 2.013.
21. 2O molecules occurs at the midpoint temperature of 117°C.
22. 16
23. Folgado, J. V.; Martinez-Tamayo, E.; Beltran-Porter, A.; Beltran-Porter, D.; Fuertes, A.; Miravitlles, C. Polyhedron 1989, 8, 1077.
24. 3): 118.8 (Y3), 121.4 (X3, 23), 123.8 (ZA), 123.9 (XS), 136.9 (X4, 25), 148.7 (Y4), 149.2 (X6), 150.1 (26), 155.2 (X2), 156.3 (Y2, 22).
25. int = 0.031, R1 = 0.061, wR2 = 0.212, and S = 1.11. Crystal data were collected on a Siemens (Bruker) SMART CCD diffractometer at 296 K.
26. Site occupancy factors: O11 0.64204, O14 0.35796, O12 0.77456, and O13 0.22544.