Torsionally responsive C 3-symmetric Azo dyes: Azo-hydrazone tautomerism, conformational switching, and application for chemical sensing

Journal of the American Chemical Society

Volumn 132, Issue 34, 2010, Pages 12133-12144

  Lee, Ho Yong ^a   Song, Xinli ^a   Park, Hyunsoo ^a   Baik, Mu Hyun ^a   Lee, Dongwhan ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMBIENT CONDITIONS; AMINE SUBSTRATES; ARYL GROUP; AZO COUPLING REACTIONS; AZO-HYDRAZONE TAUTOMERISM; BLUE SHIFT; CHEMICAL SENSING; COLOR CHANGES; COMPUTATIONAL STUDIES; CONFORMATIONAL SWITCHING; DONOR ABILITY; ELECTRONIC TRANSITION; HEXYLAMINE; HOMOLOGOUS SERIES; HYDRAZONES; HYDROGEN BONDINGS; INTRAMOLECULAR HYDROGEN; LOW ENERGIES; MOLECULAR CORE; NAKED-EYE DETECTION; NMR SPECTROSCOPY; PHLOROGLUCINOL; SPECTRAL SHIFT; STRUCTURAL DISTORTIONS; SYMMETRIC MOLECULES; TORSIONAL ANGLE; TRIETHYLAMINES; TWISTING MOTION; VOLATILE AMINES;

AZO DYES; COLORIMETRY; COMPUTATION THEORY; DENSITY FUNCTIONAL THEORY; EYE PROTECTION; HYDROGEN; HYDROGEN BONDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC POLYMERS; VAPORS; X RAY CRYSTALLOGRAPHY;

CONFORMATIONS;

AMINE; ANILINE; AZO DYE; HYDRAZONE DERIVATIVE; PHLOROGLUCINOL; AZO COMPOUND; COLORING AGENT;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; CHROMATOPHORE; CONJUGATION; DENSITY FUNCTIONAL THEORY; HYDROGEN BOND; MOLECULAR INTERACTION; MOLECULE; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTUM CHEMISTRY; TEMPERATURE DEPENDENCE; THERMODYNAMICS; TORSION; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY; CHEMISTRY; COMPUTER SIMULATION; CONFORMATION; SOLUTION AND SOLUBILITY; SYNTHESIS;

AZO COMPOUNDS; COLORING AGENTS; COMPUTER SIMULATION; CRYSTALLOGRAPHY, X-RAY; HYDRAZONES; HYDROGEN BONDING; MODELS, MOLECULAR; MOLECULAR CONFORMATION; SOLUTIONS;

EID: 77956087801     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja105121z     Document Type: Article

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