Measurement of the intramolecular isotope effect on aliphatic hydroxylation by chromobacterium violaceum phenylalanine hydroxylase

Journal of the American Chemical Society

Volumn 132, Issue 16, 2010, Pages 5584-5585

  Panay, Aram J ^a   Fitzpatrick, Paul F ^b  

^a TEXAS A AND M UNIVERSITY   (United States)

^b UNIVERSITY OF TEXAS HEALTH SCIENCE CENTER AT SAN ANTONIO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALIPHATIC CARBON; ALIPHATIC HYDROXYLATION; AROMATIC HYDROXYLATION; BENZYLIC; CALCULATED VALUES; CHROMOBACTERIUM VIOLACEUM; CYCLOHEXYL; DEUTERIUM KINETIC ISOTOPE EFFECT; GAIN INSIGHT; HYDROGEN ATOM ABSTRACTION; INTRAMOLECULAR EFFECT; IRON CENTERS; ISOTOPE EFFECT; NON-HEME IRON ENZYMES; OVERALL REACTIONS; PHENYLALANINE HYDROXYLASE; QUANTUM-MECHANICAL TUNNELING;

AMINO ACIDS; CARRIER MOBILITY; DEUTERIUM; ENZYMES; PORPHYRINS;

HYDROXYLATION;

6 METHYLTETRAHYDROPTERIN; ALIPHATIC COMPOUND; BACTERIAL ENZYME; HYDROGEN; ISOTOPE; PHENYLALANINE 4 MONOOXYGENASE;

ARTICLE; CHEMICAL STRUCTURE; CHROMOBACTERIUM VIOLACEUM; CRYSTAL STRUCTURE; ENZYME SUBSTRATE; HYDROGEN BOND; HYDROXYLATION; MEASUREMENT; NONHUMAN; CHEMISTRY; CHROMOBACTERIUM; ENZYMOLOGY; KINETICS; METABOLISM;

CHROMOBACTERIUM; HYDROXYLATION; ISOTOPES; KINETICS; PHENYLALANINE HYDROXYLASE;

EID: 77952557540     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja101563t     Document Type: Article

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