Kinetics and mechanism of michael-type reactions of ethyl propiolate with alicyclic secondary amines in H2O and MeCN: Solvent effect on reactivity and transition-state structure

Bulletin of the Korean Chemical Society

Volumn 30, Issue 12, 2009, Pages 2909-2912

  Kim, Song I ^a   Baek, Hye Won ^a   Um, Ik Hwan ^a  

^a Ewha Womans University   (South Korea)

Author keywords

Br nsted type plot; Ethyl propiolate; Kinetic isotope effect; Michael type reaction; Rate determining step

Indexed keywords

APROTIC SOLVENTS; BOND FORMATION; CONCERTED MECHANISM; CYCLIC TRANSITIONS; KINETIC ISOTOPE EFFECTS; KINETICS AND MECHANISM; MICHAEL-TYPE REACTION; MORPHOLINES; NUCLEOPHILIC ATTACK; RATE DETERMINING STEP; SECONDARY AMINES; SOLVENT EFFECTS; TRANSITION STATE STRUCTURE;

AMINES; DEUTERIUM; PROTON TRANSFER; RESPIRATORY MECHANICS;

CARRIER MOBILITY;

EID: 76649103707     PISSN: 02532964     EISSN: 12295949     Source Type: Journal    
DOI: 10.5012/bkcs.2009.30.12.2909     Document Type: Article

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