Complete mapping of the stereochemical course of retentive deprotonation/alkylation of 1H-benzo[e][1,4]diazepin-2(3H)-ones

Journal of the American Chemical Society

Volumn 131, Issue 50, 2009, Pages 18168-18176

  Hsu, Danny C ^a   Lam, Polo C H ^a   Slebodnick, Carla ^a   Carlier, Paul R ^a  

^a VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION PARAMETER; CHIRAL INTERMEDIATES; COMPLETE MAPPINGS; DENSITY-FUNCTIONAL CALCULATIONS; DIAZEPINE; ELECTROPHILES; ENANTIOPURE; ENOLATES; RING FUSION; RING INVERSION; SILYL ENOL ETHERS; STEREOLABILE; TORSIONAL EFFECT; TRANSITION STRUCTURES;

ALKYLATION; AMIDES; AMINES; ETHERS; POTASSIUM; SILANES;

X RAY CRYSTALLOGRAPHY;

1H BENZO[E][1,4]DIAZEPIN 2(3H) ONE; ALANINE DERIVATIVE; AMIDE; DIAZEPINE DERIVATIVE; ELECTROPHILE; IMIDE; POTASSIUM DERIVATIVE; POTASSIUM ENOLATE; SILANE DERIVATIVE; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CHIRALITY; CONTROLLED STUDY; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; PROTON TRANSPORT; STEREOCHEMISTRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 72449178946     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja907507j     Document Type: Article

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