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Some examples and reviews: (a) Collman, J. P.; Zhang, X.; Lee, V. J.; Uffelman, E. S.; Brauman, J. I. Science 1993, 261, 1404-1411. (b) Ojima, I. Catalytic Asymmetric Synthesis; VCH Publishers: New York, 1993. (c) Holm, R. H. Chem. Rev. 1987, 87, 1401-1449. Holm, R. R; Donahue, J. P. Polyhedron 1993, 12, 571-589. (e) Noyori, R. Asymmetric Catalysis in Organic Synthesis; Wlley: New York, 1994. (f) Pecoraro, V. L. Manganese Redox Enzymes; VCH Publishers: New York, 1992. (g) Barton, D. H. R.; Martell, A. E.; Sawyer, D. T. The Activation of Dioxygen and Homogeneous Catalytic Oxidation; Plenum Press: New York, 1993.
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Some examples and reviews: (a) Collman, J. P.; Zhang, X.; Lee, V. J.; Uffelman, E. S.; Brauman, J. I. Science 1993, 261, 1404-1411. (b) Ojima, I. Catalytic Asymmetric Synthesis; VCH Publishers: New York, 1993. (c) Holm, R. H. Chem. Rev. 1987, 87, 1401-1449. Holm, R. R; Donahue, J. P. Polyhedron 1993, 12, 571-589. (e) Noyori, R. Asymmetric Catalysis in Organic Synthesis; Wlley: New York, 1994. (f) Pecoraro, V. L. Manganese Redox Enzymes; VCH Publishers: New York, 1992. (g) Barton, D. H. R.; Martell, A. E.; Sawyer, D. T. The Activation of Dioxygen and Homogeneous Catalytic Oxidation; Plenum Press: New York, 1993.
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Some examples and reviews: (a) Collman, J. P.; Zhang, X.; Lee, V. J.; Uffelman, E. S.; Brauman, J. I. Science 1993, 261, 1404-1411. (b) Ojima, I. Catalytic Asymmetric Synthesis; VCH Publishers: New York, 1993. (c) Holm, R. H. Chem. Rev. 1987, 87, 1401-1449. Holm, R. R; Donahue, J. P. Polyhedron 1993, 12, 571-589. (e) Noyori, R. Asymmetric Catalysis in Organic Synthesis; Wlley: New York, 1994. (f) Pecoraro, V. L. Manganese Redox Enzymes; VCH Publishers: New York, 1992. (g) Barton, D. H. R.; Martell, A. E.; Sawyer, D. T. The Activation of Dioxygen and Homogeneous Catalytic Oxidation; Plenum Press: New York, 1993.
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0000753108
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PhIO and PhINTs solvolyze in methanol. See: (a) Schardt, B. C.; Hill, C. L. Inorg. Chem. 1983, 22, 1563-1565. (b) White, R. E. Inorg. Chem. 1987, 26, 3916-3919.
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Hill, C.L.2
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18
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0000885355
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PhIO and PhINTs solvolyze in methanol. See: (a) Schardt, B. C.; Hill, C. L. Inorg. Chem. 1983, 22, 1563-1565. (b) White, R. E. Inorg. Chem. 1987, 26, 3916-3919.
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37049087618
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0001652378
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tBu in 96% overall yield. See: (a) Ipatieff, V. N.; Pines, H.; Friedman, B. S. J. Am. Chem. Soc. 1938, 60, 2731-2734. (b) Iwao, M.; Iihama, T.; Mahalanabis, K. K.; Perrier, H.; Snieckus, V. J. Org. Chem. 1989, 54, 24-26. Clayden, J.; Cooney, J. J. A.; Julia, M. J. Chem. Soc., Perkin Trans. 1 1995, 7-14.
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Ipatieff, V.N.1
Pines, H.2
Friedman, B.S.3
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23
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0001978838
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tBu in 96% overall yield. See: (a) Ipatieff, V. N.; Pines, H.; Friedman, B. S. J. Am. Chem. Soc. 1938, 60, 2731-2734. (b) Iwao, M.; Iihama, T.; Mahalanabis, K. K.; Perrier, H.; Snieckus, V. J. Org. Chem. 1989, 54, 24-26. Clayden, J.; Cooney, J. J. A.; Julia, M. J. Chem. Soc., Perkin Trans. 1 1995, 7-14.
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Iwao, M.1
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Mahalanabis, K.K.3
Perrier, H.4
Snieckus, V.5
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24
-
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37049082999
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tBu in 96% overall yield. See: (a) Ipatieff, V. N.; Pines, H.; Friedman, B. S. J. Am. Chem. Soc. 1938, 60, 2731-2734. (b) Iwao, M.; Iihama, T.; Mahalanabis, K. K.; Perrier, H.; Snieckus, V. J. Org. Chem. 1989, 54, 24-26. Clayden, J.; Cooney, J. J. A.; Julia, M. J. Chem. Soc., Perkin Trans. 1 1995, 7-14.
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Clayden, J.1
Cooney, J.J.A.2
Julia, M.3
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25
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13044300277
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note
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3S: C, 35.31; H, 3.85. Found: C, 34.93; H, 4.10.
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26
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0000048608
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This decreased sensitivity to water is analogous to the added stability imparted by intramolecular secondary Bi⋯N bonding in a bismuth tosylimide. See: Ikegami, T.; Suzuki, H. Organometallics 1998, 17, 1013-1017.
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Organometallics
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Ikegami, T.1
Suzuki, H.2
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27
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84989051479
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(a) Katritzky, A. R.; Gallos, J. K.; Durst, H. D. Magn. Reson. Chem. 1989, 27, 815-822.
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Katritzky, A.R.1
Gallos, J.K.2
Durst, H.D.3
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0000038239
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(b) Mishra, A. K.; Olmstead, M. M.; Ellison, J. J.; Power, P. P. Inorg. Chem. 1995, 34, 3210-3214.
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Mishra, A.K.1
Olmstead, M.M.2
Ellison, J.J.3
Power, P.P.4
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29
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13044305325
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note
-
3 using a Bruker SMART Platform with CCD 1K detector and Mo radiation with graphite monochromator, 2Θ < 60°. Final refinement for 287 parameters converged to R1 = 0.0403 (3575 reflections with I > 2σ(1)), and wR2 = 0.0746 (all data).
-
-
-
-
30
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13044295459
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For details and related references see Supporting Information
-
For details and related references see Supporting Information.
-
-
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31
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13044263907
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note
-
(a) L = 2, 2′-isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline].
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32
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11644312278
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(b) Evans, D. A.; Faul, M. M.; Bilodeau, M, T. J. Am. Chem. Soc. 1994, 116, 2742-2753.
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Evans, D.A.1
Faul, M.M.2
Bilodeau, M.T.3
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0343341049
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Zhang, W.; Loebach, J. L.; Wilson, S. R.; Jacobsen, E. N. J. Am. Chem. Soc. 1990, 112, 2801-2803.
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J. Am. Chem. Soc.
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Zhang, W.1
Loebach, J.L.2
Wilson, S.R.3
Jacobsen, E.N.4
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34
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13044305324
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note
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6 mixture), 135.0, 148.0.
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37
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0033118620
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Francis, M. B.; Jacobsen, E. N. Angew. Chem., Int. Ed. Engl. 1999, 38, 937-941.
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Francis, M.B.1
Jacobsen, E.N.2
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38
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0001082990
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Recent exciting work has established that introduction of chiral dialkyl ether groups (for secondary bonding to I(III) center) into analogues of Koser's reagent ([PhI(OH)(OTs)]) can promote asymmetric oxytosylation reactions. See: (a) Hirt, U. H.; Spingler, B.; Wirth, T. J. Org. Chem. 1998, 63, 7674-7679. (b) Wirth, T.; Hirt, U. H. Tetrahedron Asym. 1997, 8, 23-26.
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J. Org. Chem.
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Hirt, U.H.1
Spingler, B.2
Wirth, T.3
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39
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0031016525
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Recent exciting work has established that introduction of chiral dialkyl ether groups (for secondary bonding to I(III) center) into analogues of Koser's reagent ([PhI(OH)(OTs)]) can promote asymmetric oxytosylation reactions. See: (a) Hirt, U. H.; Spingler, B.; Wirth, T. J. Org. Chem. 1998, 63, 7674-7679. (b) Wirth, T.; Hirt, U. H. Tetrahedron Asym. 1997, 8, 23-26.
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Tetrahedron Asym.
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, pp. 23-26
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Wirth, T.1
Hirt, U.H.2
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