Stabilisation of a highly reactive bis(μ-oxo)dicopper(III) species at room temperature by electronic and steric constraint of an unconventional nitrogen donor ligand

Chemistry - A European Journal

Volumn 15, Issue 35, 2009, Pages 8678-8682

  Herres Pawlis, Sonja ^a   Binder, Stephan ^b,c   Eich, Andreas ^b,c   Haase, Roxana ^a   Schulz, Benjamin ^b,c   Wellenreuther, Gerd ^d   Henkel, Gerald ^a   Rübhausen, Michael ^b,c   Meyer Klaucke, Wolfram ^d  

^a UNIVERSITY OF PADERBORN   (Germany)

^b UNIVERSITY OF HAMBURG   (Germany)

^c Center for Free Electron Laser Science   (Germany)

^d EUROPEAN MOLECULAR BIOLOGY LABORATORY   (Germany)

Author keywords

Copper; Exafs spectroscopy; Huang rhys parameter; Oxygen; Raman spectroscopy

Indexed keywords

CHARGE-TRANSFER BANDS; CORE COMPLEX; DICOPPER; DOUBLE RESONANCE; ENERGY DIFFERENCES; EXAFS; EXAFS SPECTROSCOPY; EXCITATION WAVELENGTH; HUANG-RHYS PARAMETER; NITROGEN-DONOR LIGANDS; RAMAN SIGNAL; RESONANCE RAMAN; RESONANCE RAMAN SPECTROSCOPY; RESONANT RAMAN; RESONANT RAMAN SCATTERING; ROOM TEMPERATURE; STABILISATION; STERIC CONSTRAINT; THERMALLY STABLE; TIME-DEPENDENT; UV REGION;

EXTENDED X RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY; OXYGEN; RAMAN SCATTERING; RAMAN SPECTROSCOPY; RESONANCE; STRUCTURAL DYNAMICS;

ELECTRON ENERGY LOSS SPECTROSCOPY;

COPPER; LIGAND; NITROGEN; ORGANOMETALLIC COMPOUND; OXYGEN;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; RAMAN SPECTROMETRY;

COPPER; LIGANDS; MOLECULAR STRUCTURE; NITROGEN; ORGANOMETALLIC COMPOUNDS; OXYGEN; SPECTRUM ANALYSIS, RAMAN;

EID: 69749115265     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200901092     Document Type: Article

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