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note
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a) Resonance-Raman spectra are severely affected by fluorescence emission and thus not suited to contribute to the P-core/ O-core question.
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note
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b) The k values for 1-3 were determined five times for each temperature step of 5 K between 193 K and 233 K. The average k values were calculated and plotted in an Eyring plot (see Supporting Information). The temperature deviation was estimated to be 0.2 K.
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