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Substitution at the mete-position of the phenyl rings on phosphorous atoms in the xy-Xantphos ligand is thought to be important for the high activity. Use of tol-Xantphos {4,5-bis[bis(4-mcthylphcnyl)-phosphino]-9,9- dimethylxanthene} instead of xy-Xantphos as the ligand resulted in lower activity.
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Bürgi and co-workers discussed the elongation of the Au - CI bond in AuCl(transphos) [transphos: 2, ll-bis(diphenylphosphino-methyl)benzo[C]- phenanthrene], see ref 26a, See also: DeStefano, N. J.; Johnson, D. K.; Lane, R. M.; Venanzi, L. M. Helv. Chim. Acta 1976, 59, 2674-2682.
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4 to the reaction mixture of 1b and a hydrosilane or the addition of methanol to the reaction mixture of 1b and a deuteriosilane.
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4 to the reaction mixture of 1b and a hydrosilane or the addition of methanol to the reaction mixture of 1b and a deuteriosilane.
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119
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85036813184
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121
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85036841731
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3. Although the experiments for Figure 11 c were carried out under almost dark conditions, the yields of 7b at long reaction times (240 and 300 min) probably include the product of this photoinduced side reaction.
-
3. Although the experiments for Figure 11 c were carried out under almost dark conditions, the yields of 7b at long reaction times (240 and 300 min) probably include the product of this photoinduced side reaction.
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