Reactions of a stable monomeric gold(I) hydride complex

Angewandte Chemie - International Edition

Volumn 47, Issue 46, 2008, Pages 8937-8940

  Tsui, Emily Y ^a   Müller, Peter ^a   Sadighi, Joseph P ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

Carbene ligands; Diazo compounds; Gold; Hydrides; Insertion

Indexed keywords

GOLD; HYDRIDES; HYDROGEN; LIGANDS; TRANSITION METAL COMPOUNDS; TRANSITION METALS;

A STABLES; CARBENE LIGANDS; DIAZO COMPOUNDS; HYDRIDE COMPLEXES; INSERTION; N-HETEROCYCLIC CARBENE; WIDER RANGES;

GOLD COMPOUNDS;

EID: 57349107281     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200803842     Document Type: Article

References (54)

1. a) H. Ito, K. Takagi, T. Miyahara, M. Sawamura, Org. Lett. 2005, 7, 3001-3004;
2. b) A. S. K. Hashmi, G. J. Hutchings, Angew. Chem. 2006, 118, 8064-8105;
3. Angew. Chem. Int. Ed. 2006, 45, 7896-7936, and references therein.
4. a) R. T. Baker, P. Nguyen, T. B. Marder, S. A. Westcott, Angew. Chem. 1995, 107, 1451-1452;
5. Angew. Chem. Int. Ed. Engl. 1995, 34, 1336-1338;
6. b) B. M. Wile, R. McDonald, M. J. Ferguson, M. Stradiotto, Organometallics 2007, 26, 1069-1076.
7. a) U. Ringström, Nature 1963, 198, 981;
8. b) U. Ringström, Ark. Fys. 1964, 27, 227-265.
9. a) H. G. Raubenheimer, S. Cronje in Gold, Progress in Chemistry, Biochemistry and Technology (Ed.: H. Schmidbaur), Wiley, Chichester, 1999, pp. 557-632;
10. b) P. Pyykk K, Angew. Chem. 2004, 116, 4512-4557;
11. Angew. Chem. Int. Ed. 2004, 43, 4412-4456, and references therein.
12. a) X. Wang, L. Andrews, J. Am. Chem. Soc. 2001, 123, 12899-12900;
13. b) X. Wang, L. Andrews, Angew. Chem. 2003, 115, 5359-5364;
14. Angew. Chem. Int. Ed. 2003, 42, 5201-5206;
15. c) L. Andrews, X. Wang, J. Am. Chem. Soc. 2003, 125, 11751-11760.
16. a) H. Lehner, D. Matt, P. S. Pregosin, L. M. Venanzi, A. Albinati, J. Am. Chem. Soc. 1982, 104, 6825-6827;
17. b) A. Albinati, S. Chaloupka, A. Currao, W. T. Klooster, T. F. Koetzle, R. Nesper, L. M. Venanzi, Inorg. Chim. Acta 2000, 300-302, 903-911;
18. c) B. D. Alexander, B. J. Johnson, S. M. Johnson, A. L. Casalnuovo, L. H. Pignolet, J. Am. Chem. Soc. 1986, 108, 4409-4417.
19. G. N. Khairallah, R. A. J. O'Hair, M. I. Bruce, Dalton Trans. 2006, 3699-3707.
20. N. P. Mankad, D. S. Laitar, J. P. Sadighi, Organometallics 2004, 23, 3369-3371.
21. a) M. V. Baker, P. J. Barnard, S. K. Brayshaw, J. L. Hickey, B. W. Skelton, A. H. White, Dalton Trans. 2005, 37-43;
22. b) D. S. Laitar, P. Müller, T. G. Gray, J. P. Sadighi, Organometallics 2005, 24, 4503-4505;
23. c) P. de Frémont, R. Singh, E. D. Stevens, J. L. Petersen, S. P. Nolan, Organometallics 2007, 26, 1376-1385;
24. d) I. J. B. Lin, C. S. Vasam, Can. J. Chem. 2005, 83, 812-825, and references therein.
25. P. de Frémont, N. M. Scott, E. D. Stevens, S. P. Nolan, Organometallics 2005, 24, 2411-2418.
26. K. P. Huber, G. Herzberg in Molecular Spectra and Molecular Structure IV. Constants of Diatomic Molecules; Van Nostrand Reinhold, New York, 1979, pp. 54-56.
27. W. A. Herrmann, C. Köcher, Angew. Chem. 1997, 109, 2256-2282;
28. Angew. Chem. Int. Ed. Engl. 1997, 36, 2162-2187.
29. CCDC-664588 (2), 664589 (4), 664590 (5), 664591 (6) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
30. I distances: a) M. N. I. Khan, S. Wang, J. P. Fackler, Inorg. Chem. 1989, 28, 3579-3588;
31. b) D. D. Heinrich, J.-C. Wang, J. P. Fackler, Acta Crystallogr. Sect. C 1990, 46, 1444-1447;
32. c) L. Hao, R. J. Lachicotte, H. J. Gysling, R. Eisenberg, Inorg. Chem. 1999, 38, 4616-4617.
33. M. H. Chisholm, H. C. Clark, Acc. Chem. Res. 1973, 6, 202-209, and references therein.
34. A. D. Selmeczy, W. D. Jones, Inorg. Chim. Acta 2000, 300-302, 138-150, and references therein.
35. a) H. C. Clark, C. S. Wong, J. Am. Chem. Soc. 1977, 99, 7073-7074;
36. b) H. C. Clark, G. Ferguson, A. B. Goel, E. G. Janzen, H. Ruegger, P. Y. Siew, C. S. Wong, J. Am. Chem. Soc. 1986, 108, 6961-6972.
37. J. M. Huggins, R. G. Bergman, J. Am. Chem. Soc. 1981, 103, 3002-3011.
38. N. Nishina, Y. Yamamoto, Angew. Chem. 2006, 118, 3392-3395;
39. Angew. Chem. Int. Ed. 2006, 45, 3314-3317.
40. a) M. R. Fructos, T. R. Belderrain, P. de Frémont, N. M. Scott, S. P. Nolan, M. M. Díaz-Requejo, P. J. Pérez, Angew. Chem. 2005, 117, 5418-5422;
41. Angew. Chem. Int. Ed. 2005, 44, 5284-5288;
42. b) M. R. Fructos, P. de Frémont, S. P. Nolan, M. M. Díaz-Requejo, P. J. Pérez, Organometallics 2006, 25, 2237-2241;
43. c) P. de Frémont, E. D. Stevens, M. R. Fructos, M. M. Díaz-Requejo, P. J. Pérez, S. P. Nolan, Chem. Commun. 2006, 2045-2047.
44. a) J. Lorberth, J. Organomet. Chem. 1971, 27, 303-325;
45. b) P. Krommes, J. Lorberth, J. Organomet. Chem. 1975, 97, 59-65;
46. c) K. Jones, M. F. Lappert, J. Chem. Soc. 1965, 1944-1951.
47. a) U. Schöllkopf, H. Frasnelli, Angew. Chem. 1970, 82, 291;
48. Angew. Chem. Int. Ed. Engl. 1970, 9, 301-302;
49. b) E. Müller, D. Lusteck, Chem. Ber. 1954, 87, 1887-1895.
50. a) T. DoMinh, O. P. Strausz, H. E. Gunning, Tetrahedron Lett. 1968, 9, 5237-5242;
51. b) U. Schöllkopf, N. Rieber, Angew. Chem. 1967, 79, 238-239.
52. a) U. Schöllkopf, N. Rieber, Chem. Ber. 1969, 102, 488-493;
53. b) M. Regitz, A. Liedhegener, U. Eckstein, M. Martin, W. Anschütz, Justus Liebigs Ann. Chem. 1971, 748, 207-210.
54. S. Komiya, M. Iwata, T. Sone, A. Fukuoka, J. Chem. Soc. Chem. Commun. 1992, 1109-1110.