Solution Structure of Coinage Metal-Phosphine Complexes

Journal of the American Chemical Society

Volumn 92, Issue 13, 1970, Pages 4114-4115

  Muetterties, E L ^a   Alegranti, C W ^a  

^a DUPONT COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001569108     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00716a052     Document Type: Letter

References (4)

1. This is based on estimation of the amount of s character in the Ag-P bond without any adjustment for changes in the effective nuclear charge on the met al. In those instances where the anion is bound, an electronegativity effect (or strength of the AgX bond) is operating and the coupling constants are not amenable to a simplistic analysis, at least in a quantitative sense. For reference to similar analyses in organic compounds, cf. N. Muller and D. E. Pritchard, J. Chem. Phys., 31, 768 (1959).
2. F. N. Tebbe and E. L. Muetterties, Inorg. Chem., 9, 629 (1970).
3. S. J. Lippard and K. M. Melmed, Inorg. Chem., 8, 2755 (1969).
4. D. F. Lewis, S. J. Lippard, and P. S. Welcker, J. Amer. Chem. Soc., 92, 3805 (1970), report the crystal structure of this unusual dimer based on the triphenylphosphine ligand.