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33751154561
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The presence of bis-crown-3 ether moieties is known to reduce molecular motion in the calix[4]arene series, see
-
The presence of bis-crown-3 ether moieties is known to reduce molecular motion in the calix[4]arene series, see: Arduini, A.; Fabbi, M.; Mantovani, M.; Mirone, L.; Pochini, A.; Secchi, A.; Ungaro, R. J. Org. Chem. 1995, 60, 1454-1457.
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71
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66249125256
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+
-
+.
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-
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72
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-
3242766320
-
-
+⊂10] complexes were found to be broad, as a result of a faster exchange rate with respect to the other cations. Addition of an excess of sodium picrate resulted, however, in a sharpening of the peaks. This is not the first example observed for calixcrowns, see
-
+⊂10] complexes were found to be broad, as a result of a faster exchange rate with respect to the other cations. Addition of an excess of sodium picrate resulted, however, in a sharpening of the peaks. This is not the first example observed for calixcrowns, see: Arnaud-Neu, F.; Ferguson, G.; Fuangswasdi, S.; Notti, A.; Pappalardo, S.; Parisi, M. F.; Petringa, A. J. Org. Chem. 1998, 63, 7770-7779.
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Petringa, A.7
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73
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66249144924
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-
3 to be able to observe the NH resonances and maximize, at the same time, the anion-ureido binding interactions
-
3 to be able to observe the NH resonances and maximize, at the same time, the anion-ureido binding interactions.
-
-
-
-
74
-
-
66249096218
-
-
3OD, and consequently their resonances are not observable
-
3OD, and consequently their resonances are not observable.
-
-
-
-
75
-
-
66249106955
-
-
Host-guest complexation was judged to take place with a 1:1 stoichiometry on the basis of the fact that the addition of an excess of guest salt (2 equiv) to 10 (1 equiv) caused the disappearance of all the resonances accounting for the free host and did not induce any detectable chemical shift variation on those referring to the complexed species
-
Host-guest complexation was judged to take place with a 1:1 stoichiometry on the basis of the fact that the addition of an excess of guest salt (2 equiv) to 10 (1 equiv) caused the disappearance of all the resonances accounting for the free host and did not induce any detectable chemical shift variation on those referring to the complexed species.
-
-
-
-
76
-
-
66249128169
-
-
+complex
-
+complex.
-
-
-
-
77
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-
0041766638
-
-
and references therein
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Shaik, S. Angew. Chem., Int. Ed. 2003, 42, 3208-3215, and references therein.
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Shaik, S.1
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Potkin, S. G.; Karoum, F.; Chuang, L. W.; Cannon-Spoor, H. E.; Phillips, I.; Wyatt, R. J. Science 1979, 206, 470-471.
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Potkin, S.G.1
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Phillips, I.5
Wyatt, R.J.6
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Spartan '06; Wavefunction, Inc.: Irvine, CA, 2006 (http://www.wavefun. com).
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Spartan '06
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34247580691
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-
For calculations on similar compounds, see
-
For calculations on similar compounds, see: Yakovenko, A. V.; Boyko, V. I.; Kalchenko, V. I.; Baldini, L.; Casnati, A.; Sansone, F.; Ungaro, R. J. Org. Chem. 2007, 72, 3223-3231.
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Sansone, F.6
Ungaro, R.7
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