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0037659051
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note
-
ipd is small, [2-TFA] may be calculated as in (a).
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21
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0038334705
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note
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1H NMR spectra under experimental conditions, indicating no interaction between macrocycle and salt.
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22
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4243573316
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Patai, S., Ed.; Wiley, Chichester, U.K.
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For a brief discussion on ion pairing of complexes, see: Vögtle, F.; Weber, E. In Chemistry of Ethers, Crown Ethers, Hydroxyl Groups and Their Sulphur Analogues; Patai, S., Ed.; Wiley, Chichester, U.K., 1980; Vol. 1, pp 120-121.
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Vögtle, F.1
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23
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0348070784
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This equilibrium treatment of pseudorotaxane formation has not appeared in the literature to our knowledge, although ion pairing of 2-Cl formed the basis of a reported pseudorotaxane fluorescence sensor. Montaldi, M.; Prodi, L. A. Chem. Commun. 1998, 1461-1462.
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24
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21844502462
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A similar derivation was reported for complexation of smaller crowns with alkalai metal salts, but only up to eq 2a and it was not used analytically to estimate the constants. D'Aprano, A.; Salomon, M.; Mauro, V. J. Solution Chem. 1995, 24, 685-702.
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0038673225
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-
note
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ap[H] = 1, are produced.
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26
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0038334707
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note
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See Supporting Information for a description of the error analysis.
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28
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0037659054
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note
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As this is an approximation, we are currently pursuing the use of curve fitting to better fit our data to eq 2d across the entire range.
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29
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0038673228
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note
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See Supporting Information for respective eq 2g plots.
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0038334708
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note
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The poor solubility of 2-Cl renders us unable to observe complexation over a broad enough range of concentrations to implement the reported equilibrium treatment.
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