Efficient ion-pair extraction of potassium chloride from aqueous phase into nitrobenzene containing dicyclohexyl-18-crown-6 as cation binder and diphenylthiourea as anion binder

Analytical Sciences

Volumn 15, Issue 12, 1999, Pages 1185-1189

  Murad, Mihab M ^a   Hayashita, Takashi ^a   Shigemori, Kazuki ^a   Nishizawa, Seiichi ^a   Teramae, Norio ^a  

^a TOHOKU UNIVERSITY   (Japan)

Author keywords

Anion recognition; Crown ether; Hydrogen bonding; Ion pair extraction; Thiourea receptor

Indexed keywords

CHLORINE COMPOUNDS; CROWN ETHERS; HYDROGEN BONDS; LIQUIDS; NEGATIVE IONS; NITROBENZENE; POTASH; POTASSIUM CHLORIDE; SALTS;

ANION RECOGNITION; DICYCLOHEXYL-18-CROWN-6; EXTRACTION SELECTIVITY; HYDROGEN BONDING INTERACTIONS; ION PAIR EXTRACTION; LIQUID-LIQUID EXTRACTION; QUALITATIVE EVALUATIONS; SOLID-LIQUID EXTRACTION;

EXTRACTION;

ANION; CATION; CROWN ETHER; NITROBENZENE; POTASSIUM CHLORIDE; THIOUREA DERIVATIVE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL BINDING; CHEMICAL STRUCTURE; EQUILIBRIUM CONSTANT; EXTRACTION; HYDROGEN BOND; ION PAIR EXTRACTION; LIQUID; LIQUID LIQUID EXTRACTION; MOLECULAR RECOGNITION; PROTON NUCLEAR MAGNETIC RESONANCE; SOLID STATE;

EID: 0033388426     PISSN: 09106340     EISSN: None     Source Type: Journal    
DOI: 10.2116/analsci.15.1185     Document Type: Article

References (30)

1. D. M. Rudkevich, Z. Brzozka, M. Palys, H. C. Visser, W. Verboom and D. N. Reinhoudt, Angew. Chem., Int. Ed. Engl., 33, 467 (1994).
2. J. Scheerder, J. F. J. Engbersen, A. Casnati, R. Ungaro and D. N. Reinhoudt, J. Org. Chem., 60, 6448 (1995).
3. K. I. Kinnear, D. P. Mousley, E. Arafar and J. C. Lockhart, J. Chem. Soc., Dalton Trans., 1994, 3637.
4. P. D. Beer, M. G. B. Drew, R. J. Knubley and M. I. Ogden, J. Chem. Soc., Dalton Trans., 1995, 3117.
5. P. D. Beer, F. Szemes, V. Balzani, C. M. Sala, M. G. B. Drew, S. W. Dent and M. Maestri, J. Am. Chem. Soc., 119, 11864 (1997).
6. J. E. Redman, P. D. Beer, S. W. Dent and M. G. B. Drew, Chem. Commun., 1998, 231; P. D. Beer and S. W. Dent, Chem. Commun., 1998, 825.
7. J. E. Redman, P. D. Beer, S. W. Dent and M. G. B. Drew, Chem. Commun., 1998, 231; P. D. Beer and S. W. Dent, Chem. Commun., 1998, 825.
8. J. Scheerder, J. P. M. van Duynhoven, J. F. J. Engbersen and D. N. Reinhoudt, Angew. Chem., Int. Ed. Engl., 35, 1090 (1996).
9. F. P. Schmidtchen and M. Berger, Chem. Rev., 97, 1609 (1997).
10. E. Fan, S. A. Van Arman, S. Kincaid and A. D. Hamilton, J. Am. Chem. Soc., 115, 369 (1993).
11. C. S. Wilcox, E.-I. Kim, D. Romano, L. H. Kuo, A. L. Burt and D. P. Curran, Tetrahedron, 51, 621 (1995).
12. S. Nishizawa, P. Bühlmann, K. P. Xiao and Y. Umezawa, Anal. Chim. Acta, 358, 35 (1998).
13. P. Bühlmann, S. Nishizawa, K. P. Xiao and Y. Umezawa, Tetrahedron, 53, 1647 (1997).
14. K. P. Xiao, P. Bühlmann, S. Nishizawa, S. Amemiya and Y. Umezawa, Anal. Chem., 69, 1038 (1997).
15. S. Amemiya, P. Bühlmann and Y. Umezawa, Chem. Commun., 1997, 1027.
16. R. C. Jagessar and D. H. Burns, Chem. Commun., 1997, 1685.
17. S. Nishizawa, R. Kato, T. Hayashita and N. Teramae, Anal. Sci., 14, 595 (1998).
18. S. Nishizawa and N. Teramae, Anal. Sci., 13 (supplement), 485 (1997).
19. S. Nishizawa, H. Kaneda, T. Uchida and N. Teramae, J. Chem. Soc. Perkin Trans. 2, 11, 2325 (1998).
20. H. C. Visser, D. M. Rudkevich, W. Verboom, F. de Jong and D. N. Reinhoudt, J. Am. Chem. Soc., 116, 11554 (1994).
21. E. Bakker, P. Bühlmann and E. Pretsch, Chem. Rev., 97, 3083 (1997).
22. P. Bühlmann, E. Bakker and E. Pretsch, Chem. Rev., 98, 1593 (1998).
23. C. Behringer, B. Lehmann and W. Simon, Chimia, 41, 397 (1987).
24. E. Wang and M. E. Meyerhoff, Anal. Chim. Acta, 283, 673 (1993).
25. T. Hayashita, M. Kumazawa, J. C. Lee and R. A. Bartsch, Chem. Lett., 1995, 711.
26. R. M. Izatt, J. S. Bradshaw, S. A. Nielsen, J. D. Lamb, J. J. Christensen and D. Sen, Chem. Rev., 85, 271 (1985).
27. K. A. Connors, "Binding Constants", p. 141, John Wiley & Sons, New York, 1987.
28. C. S. Wilcox, in "Frontiers in Supramolecular Chemistry", ed. H. Schneider and H. Durr, pp. 123 - 143, VCH, Weinheim, 1991.
29. D. Wegmann, H. Weiss, D. Ammann, W. E. Morf, E. Pretsch, K. Sugahara and W. Simon, Mikrochim. Acta, 3, 1 (1984); F. Hofmeister, Arch. Exp. Pathol. Pharmakol., 24, 247 (1988).
30. D. Wegmann, H. Weiss, D. Ammann, W. E. Morf, E. Pretsch, K. Sugahara and W. Simon, Mikrochim. Acta, 3, 1 (1984); F. Hofmeister, Arch. Exp. Pathol. Pharmakol., 24, 247 (1988).