Ion Pairing in Fast-Exchange Host-Guest Systems: Concentration Dependence of Apparent Association Constants for Complexes of Neutral Hosts and Divalent Guest Salts with Monovalent Counterions

Journal of the American Chemical Society

Volumn 125, Issue 47, 2003, Pages 14458-14464

  Huang, Feihe ^a   Jones, Jason W ^a   Slebodnick, Carla ^a   Gibson, Harry W ^a  

^a VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FREE DICATIONS; VIOLOGENS; X-RAY CRYSTAL STRUCTURES;

CHEMICAL MODIFICATION; COMPLEXATION; CROWN ETHERS; CRYSTAL STRUCTURE; DISSOCIATION; ION EXCHANGE; POSITIVE IONS; SOLUTIONS;

SALTS;

ACETONE; CROWN ETHER DERIVATIVE; DIVALENT CATION; FLUOROPHOSPHATE; INORGANIC SALT; ION; PARAQUAT;

ARTICLE; COMPLEX FORMATION; CONCENTRATION RESPONSE; CRYSTAL STRUCTURE; DISSOCIATION; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0344826550     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja036606f     Document Type: Article

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28. Huang, F.; Slebodnick, C.; Golen, J. A.; Rheingold, A. L.; Gibson, H. W., unpublished results.
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30. ipd.1 were determined. Errors are based on errors of the intercepts.
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35. See Supporting Information.
36. -1 in acetone at room temperature by employing the titration methodology and following the charge-transfer band (435 nm) of the complex by absorption spectroscopy.
37. -1 in acetone at room temperature by employing the titration methodology and following the charge-transfer band (437 nm) of the complex by absorption spectroscopy.
38. -1 in acetone at room temperature by employing the titration methodology and following the charge-transfer band (437 nm) of the complex by absorption spectroscopy.