Dehydrofluorination of hydrofluorocarbons by titanium alkylidynes via sequential C-H/C-F bond activation reactions. A synthetic, structural, and mechanistic study of 1,2-CH bond addition and β-fluoride elimination

Organometallics

Volumn 28, Issue 1, 2009, Pages 331-347

  Fout, Alison R ^a   Scott, Jennifer ^a   Miller, Deanna L ^a   Bailey, Brad C ^b   Pink, Maren ^a   Mindiola, Daniel J ^a  

^a INDIANA UNIVERSITY   (United States)

^b MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

4-METHYLPHENYL; ACTIVATED COMPLEXES; ACTIVATION PARAMETERS; ALKYLIDENE; ALKYLIDYNE; ALKYLIDYNES; BENZYNE; BOND ACTIVATION REACTIONS; C - H ACTIVATIONS; C-H BOND ACTIVATIONS; C-H BONDS; ELECTRON-RICH; ELEVATED TEMPERATURES; FLUOROBENZENE; HALOBENZENES; HIGHER TEMPERATURES; HYDROFLUOROCARBONS; HYDROGEN ABSTRACTIONS; MECHANISTIC STUDIES; NEOPENTANE; POSITIVE CHARGES; PSEUDO FIRST ORDERS; RATE-DETERMINING STEPS; REACTION MIXTURES; REGIO-SELECTIVE; TERMINAL OLEFINS; TRANSMETALATION;

ABSTRACTING; ACTIVATION ANALYSIS; BENZENE; CHEMICAL ACTIVATION; DERIVATIVES; FLUORINE COMPOUNDS; HYDROGEN; MECHANICS; OLEFINS; PARAFFINS; TITANIUM;

TITANIUM COMPOUNDS;

EID: 61849148181     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800910q     Document Type: Article

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