Fluorine for hydrogen exchange in the hydrofluorobenzene derivatives C 6HxF(6-x), where x = 2, 3, 4 and 5 by monomeric [1,2,4-(Me3C)3C5H2]2CeH: The solid state isomerization of [1,2,4-(Me3C)3C 5H2]2Ce(2,3,4,5-C6HF4) ...

Journal of the American Chemical Society

Volumn 130, Issue 22, 2008, Pages 7153-7165

  Werkema, Evan L ^a   Andersen, Richard A ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; DERIVATIVES; ISOMERIZATION; MONOMERS; ORGANIC SOLVENTS; SOLID STATE REACTIONS;

FLUOROBENZYNE; HYDROFLUOROBENZENE; HYDROGEN EXCHANGE;

FLUORINE COMPOUNDS;

BENZENE DERIVATIVE; BIS(1,2,4 TRI TERT BUTYLCYCLOPENTADIENYL)CERIUM; CERIUM; FLUORINE; HYDROFLUOROBENZENE DERIVATIVE; HYDROGEN; MONOMER; SOLVENT;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; ISOMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SOLID STATE; STEREOCHEMISTRY; THERMODYNAMICS;

EID: 44649135721     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja800639f     Document Type: Article

References (12)

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12. We thank a reviewer for calling our attention to the fact that the vibrational entropy of 6 is greater than that of 7.