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Volumn 321, Issue 5893, 2008, Pages 1188-1190

Hydrodefluorination of perfluoroalkyl groups using silylium-carborane catalysts

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CARBORANE DERIVATIVE; FLUORINE; HYDROGEN; SILANE DERIVATIVE;

EID: 50649087926     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1159979     Document Type: Article
Times cited : (468)

References (34)
  • 6
    • 84958634880 scopus 로고    scopus 로고
    • J. A. Gladysz, D. P. Curran, I. T. Horvath, Eds, Wiley-VCH, Weinheim, Germany
    • J. A. Gladysz, D. P. Curran, I. T. Horvath, Eds., Handbook of Fluorous Chemistry (Wiley-VCH, Weinheim, Germany, 2004).
    • (2004) Handbook of Fluorous Chemistry
  • 10
  • 15
    • 50649100853 scopus 로고    scopus 로고
    • Using textbook bond energy values from 31
    • Using textbook bond energy values from (31).
  • 17
    • 50649100352 scopus 로고    scopus 로고
    • For an overview of gas-phase C-F activation, see
    • For an overview of gas-phase C-F activation, see (33).
    • , vol.33
  • 26
    • 50649117018 scopus 로고    scopus 로고
    • Materials and methods are available as supporting material on Science Online.
    • Materials and methods are available as supporting material on Science Online.
  • 29
    • 50649107667 scopus 로고    scopus 로고
    • 3Si[carborane], a similar discrepancy between lower coordinating ability and higher activity was reported (32).
    • 3Si[carborane], a similar discrepancy between lower coordinating ability and higher activity was reported (32).
  • 34
    • 50649114381 scopus 로고    scopus 로고
    • We are thankful to the U.S. Department of Energy's Office of Basic Energy Sciences (DE-FG02-06ER15815, Research Corporation (Research Innovation Award to O.V.O, Alfred P. Sloan Foundation Sloan Research Fellowship to O.V.O, and Brandeis University for support of this research. We are indebted to S. Kunz and A. G. Redfield for their assistance with 11B NMR experiments
    • 11B NMR experiments.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.