Reaction of vinyl chloride with group 4 metal olefin polymerization catalysts

Journal of the American Chemical Society

Volumn 125, Issue 3, 2003, Pages 796-809

  Stockland Jr , Robert A ^a   Foley, Stephen R ^a   Jordan, Richard F ^a  

^a UNIVERSITY OF CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHAIN TRANSFER MECHANISM;

ALUMINUM; ANTIOXIDANTS; CATALYSTS; OLEFINS; OLIGOMERS; POLYMERIZATION; POSITIVE IONS; PROPYLENE; STOICHIOMETRY; UNSATURATED POLYMERS;

POLYVINYL CHLORIDES;

ALKENE; ALUMINUM DERIVATIVE; CHLORIDE; METAL; METHYL GROUP; POLYPROPYLENE; POLYVINYLCHLORIDE; PROPYLENE; TITANIUM DERIVATIVE; VINYL CHLORIDE; ZIRCONIUM DERIVATIVE;

ALKYLATION; ARTICLE; CATALYST; CHEMICAL REACTION; OLIGOMERIZATION; POLYMERIZATION; REACTION ANALYSIS;

EID: 0037460147     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028530d     Document Type: Article

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151. An excess of inhibitor was used because the inhibitor may be consumed by a reaction with 7 or MAO. The lack of complete inhibition in the inhibitor experiments described in ref 36 (inhibitor/Ti/Al = 1:1:10) can be ascribed to the consumption of the inhibitor by such reactions. See: (a) Mahanthappa, M. K.; Huang, K.-W.; Cole, A. P.; Waymouth, R. M. Chem. Commun. 2002, 502. (b) Ziemkowska, W. Main Group Met. Chem. 2000, 23, 337. (c) Boucher, D. L.; Brown, M. A.; McGarvey, B. R.; Tuck, D. G. J. Chem. Soc., Dalton Trans. 1999, 3445. (d) Granel, C.; Jerome, R.; Teyssie, P.; Jasieczek, C. B.; Shooter, A. J.; Haddleton, D. M.; Hastings, J. J.; Gigmes, D.; Grimaldi, S.; Tordo, P.; Greszta, D.; Matyjaszewski, K. Macromolecules 1998, 31, 7133. (e) Carrera, M. A.; Mena, M.; Royo, P.; Serrano, R. J. Organomet. Chem. 1986, 315, 329.
152. An excess of inhibitor was used because the inhibitor may be consumed by a reaction with 7 or MAO. The lack of complete inhibition in the inhibitor experiments described in ref 36 (inhibitor/Ti/Al = 1:1:10) can be ascribed to the consumption of the inhibitor by such reactions. See: (a) Mahanthappa, M. K.; Huang, K.-W.; Cole, A. P.; Waymouth, R. M. Chem. Commun. 2002, 502. (b) Ziemkowska, W. Main Group Met. Chem. 2000, 23, 337. (c) Boucher, D. L.; Brown, M. A.; McGarvey, B. R.; Tuck, D. G. J. Chem. Soc., Dalton Trans. 1999, 3445. (d) Granel, C.; Jerome, R.; Teyssie, P.; Jasieczek, C. B.; Shooter, A. J.; Haddleton, D. M.; Hastings, J. J.; Gigmes, D.; Grimaldi, S.; Tordo, P.; Greszta, D.; Matyjaszewski, K. Macromolecules 1998, 31, 7133. (e) Carrera, M. A.; Mena, M.; Royo, P.; Serrano, R. J. Organomet. Chem. 1986, 315, 329.
153. An excess of inhibitor was used because the inhibitor may be consumed by a reaction with 7 or MAO. The lack of complete inhibition in the inhibitor experiments described in ref 36 (inhibitor/Ti/Al = 1:1:10) can be ascribed to the consumption of the inhibitor by such reactions. See: (a) Mahanthappa, M. K.; Huang, K.-W.; Cole, A. P.; Waymouth, R. M. Chem. Commun. 2002, 502. (b) Ziemkowska, W. Main Group Met. Chem. 2000, 23, 337. (c) Boucher, D. L.; Brown, M. A.; McGarvey, B. R.; Tuck, D. G. J. Chem. Soc., Dalton Trans. 1999, 3445. (d) Granel, C.; Jerome, R.; Teyssie, P.; Jasieczek, C. B.; Shooter, A. J.; Haddleton, D. M.; Hastings, J. J.; Gigmes, D.; Grimaldi, S.; Tordo, P.; Greszta, D.; Matyjaszewski, K. Macromolecules 1998, 31, 7133. (e) Carrera, M. A.; Mena, M.; Royo, P.; Serrano, R. J. Organomet. Chem. 1986, 315, 329.
154. An excess of inhibitor was used because the inhibitor may be consumed by a reaction with 7 or MAO. The lack of complete inhibition in the inhibitor experiments described in ref 36 (inhibitor/Ti/Al = 1:1:10) can be ascribed to the consumption of the inhibitor by such reactions. See: (a) Mahanthappa, M. K.; Huang, K.-W.; Cole, A. P.; Waymouth, R. M. Chem. Commun. 2002, 502. (b) Ziemkowska, W. Main Group Met. Chem. 2000, 23, 337. (c) Boucher, D. L.; Brown, M. A.; McGarvey, B. R.; Tuck, D. G. J. Chem. Soc., Dalton Trans. 1999, 3445. (d) Granel, C.; Jerome, R.; Teyssie, P.; Jasieczek, C. B.; Shooter, A. J.; Haddleton, D. M.; Hastings, J. J.; Gigmes, D.; Grimaldi, S.; Tordo, P.; Greszta, D.; Matyjaszewski, K. Macromolecules 1998, 31, 7133. (e) Carrera, M. A.; Mena, M.; Royo, P.; Serrano, R. J. Organomet. Chem. 1986, 315, 329.
155. An excess of inhibitor was used because the inhibitor may be consumed by a reaction with 7 or MAO. The lack of complete inhibition in the inhibitor experiments described in ref 36 (inhibitor/Ti/Al = 1:1:10) can be ascribed to the consumption of the inhibitor by such reactions. See: (a) Mahanthappa, M. K.; Huang, K.-W.; Cole, A. P.; Waymouth, R. M. Chem. Commun. 2002, 502. (b) Ziemkowska, W. Main Group Met. Chem. 2000, 23, 337. (c) Boucher, D. L.; Brown, M. A.; McGarvey, B. R.; Tuck, D. G. J. Chem. Soc., Dalton Trans. 1999, 3445. (d) Granel, C.; Jerome, R.; Teyssie, P.; Jasieczek, C. B.; Shooter, A. J.; Haddleton, D. M.; Hastings, J. J.; Gigmes, D.; Grimaldi, S.; Tordo, P.; Greszta, D.; Matyjaszewski, K. Macromolecules 1998, 31, 7133. (e) Carrera, M. A.; Mena, M.; Royo, P.; Serrano, R. J. Organomet. Chem. 1986, 315, 329.
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