Hydrogen atom transfer reactions of a ruthenium imidazole complex: Hydrogen tunneling and the applicability of the marcus cross relation

Journal of the American Chemical Society

Volumn 130, Issue 44, 2008, Pages 14745-14754

  Wu, Adam ^a   Mayer, James M ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; AMINES; ATOMIC PHYSICS; ATOMS; COMPRESSED AIR MOTORS; DEUTERIUM; FREE RADICAL REACTIONS; HYDROGEN; NUCLEAR MAGNETIC RESONANCE; PROTON TRANSFER; REACTION KINETICS; RUTHENIUM; RUTHENIUM COMPOUNDS; THERMOCHEMISTRY; TUNNELING (EXCAVATION);

ACTIVATION PARAMETERS; APPARENT ACTIVATION ENERGIES; ARRHENIUS; BIMOLECULAR RATE CONSTANTS; CROSS RELATIONS; DEUTERIUM KINETIC ISOTOPE EFFECTS; ELECTRON TRANSFERS; EXPONENTIAL FACTORS; FLOW TECHNIQUES; HYDROGEN ATOMS; IMIDAZOLE COMPLEXES; KINETIC MEASUREMENTS; LINE BROADENING; MARCUS CROSS RELATIONS; PYRIDYL; SEMICLASSICAL LIMITS; TETRAMETHYL PIPERIDINES; TUNNELING MECHANISMS;

RATE CONSTANTS;

DEUTERIUM; HYDROGEN; PIPERIDINE DERIVATIVE; RUTHENIUM COMPLEX;

ARTICLE; CHEMICAL REACTION KINETICS; ELECTRON TRANSPORT; ISOTOPE ANALYSIS; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; TEMPERATURE DEPENDENCE;

CYCLIC N-OXIDES; HYDROGEN; IMIDAZOLES; MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLIC COMPOUNDS; PENTANONES; PYRIDINES; PYRIMIDINES; RUTHENIUM; THERMODYNAMICS;

EID: 55649104328     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja805067h     Document Type: Article

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