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-
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85037462017
-
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note
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-
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52
-
-
85037465331
-
-
note
-
(a) For the reaction of Al-R-, the polarization of the sharp signal changed from emission to absorption at ca. 800 ns and then decayed to the baseline in 2.5 μs. These results suggested that not only the T-D quenching but also the spin-selective backward ET of BRIP should generate polarization of the TEMPO moiety of A1-R·.
-
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-
-
53
-
-
85037447215
-
-
note
-
3MPTZ* with An-R· is under investigation.
-
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54
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0032236322
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-
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85037490724
-
-
Under the conditions of our TREPR measurements, the decay of signal to the baseline before the laser pulse corresponds to the establishment of the thermal equilibrium.
-
(a) Under the conditions of our TREPR measurements, the decay of signal to the baseline before the laser pulse corresponds to the establishment of the thermal equilibrium.
-
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-
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56
-
-
85037449355
-
-
5f
-
5f
-
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-
-
57
-
-
85037447403
-
-
note
-
McCN. The following values were assumed: R = 7.0 Å, r+ = 3.5 Å, r- = 3.0 Å.
-
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-
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59
-
-
85037463135
-
-
note
-
2 (this work).
-
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60
-
-
85037459114
-
-
note
-
T = 2.64 eV), because the phosphorescence spectrum of N,N′-dipentyl-pyromellitic diimide was reported to show a broad band around 500 nm.
-
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61
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-
-
85037474692
-
-
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-
-1 for such IP in MeCN at 293 K, which agrees with the observed value,
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67
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33845282242
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85037479455
-
-
note
-
̇+ exhibited MFEs quite similar to those on the R(B) values. See ref 26.
-
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-
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73
-
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85037472878
-
-
note
-
FI value and the magnitude of MFEs.
-
-
-
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74
-
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85037486699
-
-
note
-
̇--R· had almost disappeared by 1.8 μs.
-
-
-
-
75
-
-
85037462503
-
-
note
-
0 was independent of B.
-
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78
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0001488975
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87
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85037449633
-
-
note
-
3MPTZ* with Al in the presence of 1 mM of TEMPO were almost the same as the corresponding values without TEMPO.
-
-
-
-
88
-
-
85037468685
-
-
note
-
1/2 mixing and undergoes the backward ET reaction.
-
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0343185703
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90
-
-
85037463177
-
-
note
-
3MPTZ* is unknown. However; the TREPR spectrum observed in the quenching of the TI state of unsubstituted phenothiazine by TEMPO in 2-PrOH also exhibits a net emissive three-line signal with an almost 1:1:1 ratio due to TEMPO.48c
-
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-
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91
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0000761335
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85037468497
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-
note
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48c
-
-
-
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94
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0005533748
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Fujitsu Ltd., Japan
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WinMOPAC Ver. 2.0, Fujitsu Ltd., Japan, 1997.
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WinMOPAC Ver. 2.0
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95
-
-
85037447177
-
-
note
-
̇- by UHF calculation. The same geometry was used as the case of the point-dipole approximation. The calculated values are |D′| = 5.65 and |E′| = 0.06 mT for the extended conformer, while |D′| = 8.09 and |E′| = 0.21 mT for the folded one.
-
-
-
-
96
-
-
85037450937
-
-
note
-
̇--R·] estimated with eq 6a.
-
-
-
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98
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0033518578
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0001118296
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85037476262
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note
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49
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106
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0000796701
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-) of TEMPO (R·) is readily protonated to give the corresponding hydroxylamine (RH), which exhibits no optical absorption in visible region. Fish, J. R.; Swarts, S. G.; Sevilla, M. D.; Malinski, T. J. Phys. Chem. 1988, 92, 3745-3751.
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107
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0343185705
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(b) TEMPO is reduced more easily in hydroxylic solvents than in aprotic solvents. For example, the reduction potential of TEMPO measured in MeOH is less negative by 1.2 V than that obtained in THF. Green, S.; Fox, M. A. J. Phys. Chem. 1999, 103, 5416-5424.
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