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A related class of PCET reactions is ET modulated by a hydrogen-bonded interface, e.g., with 4-carboxybipyridine-Ru complexes: (a) Kirby, J. P.; Roberts, J. A.; Nocera, D. G. J. Am. Chem. Soc. 1997, 119, 9230-9236.
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Full details and explanation are given in the Supporting Information
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Full details and explanation are given in the Supporting Information.
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3ArOH) = 28: Bordwell, F. G.; Cheng, J.-P. J. Am. Chem. Soc. 1991, 113, 1736-1743.
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This ΔE1/2 implies that the pK a(RuII)-pKaRuIII, 2.2 units.1c
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