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Volumn 130, Issue 23, 2008, Pages 7210-7211

Facile concerted proton-electron transfers in a ruthenium terpyridine-4′-carboxylate complex with a long distance between the redox and basic sites

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; RIBONUCLEOTIDE REDUCTASE; RUTHENIUM COMPLEX;

EID: 44949248367     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja801672w     Document Type: Article
Times cited : (54)

References (37)
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    • (a) Free Radicals; Kochi, J. K. Ed.; Wiley: New York, 1973.
    • (1973) Free Radicals
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    • Hynes, J. T, Klinman, J. P, Limbach, H.-H, Schowen, R. L. Eds, Wiley-VCH: Weinheim, Germany
    • (b) Hydrogen-Transfer Reactions; Hynes, J. T., Klinman, J. P., Limbach, H.-H., Schowen, R. L. Eds.; Wiley-VCH: Weinheim, Germany, 2007.
    • (2007) Hydrogen-Transfer Reactions
  • 6
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    • 10.
    • 10.
  • 20
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    • A related class of PCET reactions is ET modulated by a hydrogen-bonded interface, e.g., with 4-carboxybipyridine-Ru complexes: (a) Kirby, J. P.; Roberts, J. A.; Nocera, D. G. J. Am. Chem. Soc. 1997, 119, 9230-9236.
    • A related class of PCET reactions is ET modulated by a hydrogen-bonded interface, e.g., with 4-carboxybipyridine-Ru complexes: (a) Kirby, J. P.; Roberts, J. A.; Nocera, D. G. J. Am. Chem. Soc. 1997, 119, 9230-9236.
  • 23
    • 44949154145 scopus 로고    scopus 로고
    • Full details and explanation are given in the Supporting Information
    • Full details and explanation are given in the Supporting Information.
  • 25
    • 0000831295 scopus 로고    scopus 로고
    • Selected isolated oxidants (ref 10): (a) Moyer, B. A.; Meyer, T. J. J. Am. Chem. Soc. 1978, 100, 3601-3603.
    • Selected isolated oxidants (ref 10): (a) Moyer, B. A.; Meyer, T. J. J. Am. Chem. Soc. 1978, 100, 3601-3603.
  • 28
    • 0000161895 scopus 로고    scopus 로고
    • 3ArOH) = 28: Bordwell, F. G.; Cheng, J.-P. J. Am. Chem. Soc. 1991, 113, 1736-1743.
    • 3ArOH) = 28: Bordwell, F. G.; Cheng, J.-P. J. Am. Chem. Soc. 1991, 113, 1736-1743.
  • 30
    • 37049088614 scopus 로고    scopus 로고
    • -) = -0.707 V: Niyazymbetov, M. E.; Evans, D. H. J. Chem. Soc., Perkin Trans. 2 1993, 1333-1338.
    • -) = -0.707 V: Niyazymbetov, M. E.; Evans, D. H. J. Chem. Soc., Perkin Trans. 2 1993, 1333-1338.
  • 31
    • 44949099096 scopus 로고    scopus 로고
    • 10
    • 10
  • 33
    • 44949095028 scopus 로고    scopus 로고
    • This ΔE1/2 implies that the pK a(RuII)-pKaRuIII, 2.2 units.1c
    • 1c
  • 36
    • 44949212532 scopus 로고    scopus 로고
    • See refs 5c, 7
    • (c) See refs 5c, 7.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.