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Only a few catalytic reactions were thus far reported, not resulting in an opening of at least one cyclopropane ring: (a) Takeuchi, D.; Anada, K.; Osakada, K. Angew. Chem., Int. Ed. 2004, 43, 1233-1235.
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A recent elegant intramolecular rhodium-catalyzed C-H bond activation with alkylidenecyclopropanes also resulted in ring opening of the cyclopropane moiety; Aïssa, C.; Fürstner, A. J. Am. Chem. Soc. 2007, 129, 14836-14837.
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2 and PPhs yielded quantitative ring opening of 2, along with its polymerization, even at 50 °C reaction temperature.
-
2 and PPhs yielded quantitative ring opening of 2, along with its polymerization, even at 50 °C reaction temperature.
-
-
-
-
50
-
-
61349186745
-
-
Here, only undesired by-products due to Diels-Alder [4 + 2] cycloadditions of 2-phenylbuta-l,4-diene were obtained (see the Supporting Information).
-
Here, only undesired by-products due to Diels-Alder [4 + 2] cycloadditions of 2-phenylbuta-l,4-diene were obtained (see the Supporting Information).
-
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51
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61349193564
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CCDC-678126 (b), -688765 (13b), and -678125 (14) contain the supplementary crystallographic data for these compounds. The data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam. ac-uk.
-
CCDC-678126 (b), -688765 (13b), and -678125 (14) contain the supplementary crystallographic data for these compounds. The data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam. ac-uk.
-
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54
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0035540115
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A deuterium-proton exchange was previously observed in hydroarylations of simple alkenes: (a) Kakiuchi, F.; Ohtaki, H.; Sonoda, M.; Chatani, N.; Murai, S. Chem. Lett. 2001, 30, 918-919.
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A deuterium-proton exchange was previously observed in hydroarylations of simple alkenes: (a) Kakiuchi, F.; Ohtaki, H.; Sonoda, M.; Chatani, N.; Murai, S. Chem. Lett. 2001, 30, 918-919.
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7] as solvent, proton-deuterium exchange on pyridines 1a and 3a was not observed under otherwise identical reaction conditions.
-
7] as solvent, proton-deuterium exchange on pyridines 1a and 3a was not observed under otherwise identical reaction conditions.
-
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57
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38149032348
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-
The high selectivity obtained with monophosphine biphenyl ligand 11 is likely due to formation of arene-tethered ruthenium phosphine complexes. For the use of comparable phosphines in ruthenium catalysis, see: (a) Aikawa, K.; Kaito, I.; Mikami, K. Chem. Lett. 2007, 36, 1482-1483.
-
The high selectivity obtained with monophosphine biphenyl ligand 11 is likely due to formation of arene-tethered ruthenium phosphine complexes. For the use of comparable phosphines in ruthenium catalysis, see: (a) Aikawa, K.; Kaito, I.; Mikami, K. Chem. Lett. 2007, 36, 1482-1483.
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The corresponding arene-tethered ruthenium phosphine complex derived from ligand 11 was isolated and unambigiously characterized: Kozhushkov, S. I.; Yufit, D. S.; Ackermann, L. Unpublished results.
-
The corresponding arene-tethered ruthenium phosphine complex derived from ligand 11 was isolated and unambigiously characterized: Kozhushkov, S. I.; Yufit, D. S.; Ackermann, L. Unpublished results.
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