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Volumn , Issue 31, 2008, Pages 4079-4094

N-heterocyclic carbene complexes of rhodium: Structure, stability and reactivity

Author keywords

[No Author keywords available]

Indexed keywords

N-HETEROCYCLIC CARBENE COMPLEXES; ORGANOMETALLIC CHEMISTRY; SYNTHETIC ROUTES;

EID: 49149089975     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b802114g     Document Type: Article
Times cited : (110)

References (98)
  • 18
    • 33745688099 scopus 로고    scopus 로고
    • N-heterocyclic carbenes in transition metal catalysis
    • F. Glorius, Springer Verlag, Heidelberg
    • N-Heterocyclic Carbenes in transition Metal Catalysis, F. Glorius, Top. Organomet. Chem., Springer Verlag, Heidelberg, 2007
    • (2007) Top. Organomet. Chem.
  • 24
    • 49149088865 scopus 로고
    • Germany
    • O. Roelen, Germany, 1938, EU pat. 849 548
    • (1938)
    • Roelen, O.1
  • 26
    • 0004147148 scopus 로고    scopus 로고
    • Dordrecht, Although the analgesic properties of most of this class of compounds have been ascribed solely to the S-enantiomer, one of the largest selling NSAIDs, ibuprofen, is sold as the racemate because racemase enzymes in the body convert the inactive R-enantiomer into the active S-form. Thus, enantioselective synthesis of this compound in particular are not required, although high regioselectivity for the branched isomer is always essential
    • P. W. N. M. van Leeuwen and C. Claver, in Rhodium Catalysed Hydroformylation, Dordrecht, 2000
    • (2000) Rhodium Catalysed Hydroformylation
    • Van Leeuwen, P.W.N.M.1    Claver In, C.2
  • 82
    • 33749870540 scopus 로고    scopus 로고
    • Although it has been suggested that CuCl is instead acting as a carbene sponge, the activity obtained is higher than that observed in its absence. If it was acting as a carbene sponge generating Wilkinson's catalyst, identical or lower activity would be expected. Furthermore, since phosphine dissociation is significantly faster than carbene dissociation, reaction with phosphine is more likely
    • X. Y. Yu B. O. Patrick B. R. James Organometallics 2006 25 4870
    • (2006) Organometallics , vol.25 , pp. 4870
    • Yu, X.Y.1    Patrick, B.O.2    James, B.R.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.