Triazolediylidenes: A versatile class of ligands for the preparation of discrete molecules of homo- and hetero-binuclear complexes for improved catalytic applications

Angewandte Chemie - International Edition

Volumn 46, Issue 20, 2007, Pages 3729-3731

  Mas Marzá, Elena ^a   Mata, José A ^a   Peris, Eduardo ^a  

^a UNIVERSITAT JAUME I   (Spain)

Author keywords

Carbene ligands; Heterocycles; Homogeneous catalysis; Iridium; Rhodium

Indexed keywords

CATALYST ACTIVITY; IRIDIUM; RHODIUM;

CARBENE LIGANDS; DINUCLEAR COMPLEXES; HETEROCYCLES;

LIGANDS;

EID: 34250841727     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200700535     Document Type: Article

References (30)

1. W. A. Herrmann, C. Kocher, Angew. Chem. 1997, 109, 2256;
2. Angew. Chem. Int. Ed. Engl. 1997, 36, 2162;
3. W. A. Herrmann, Angew. Chem. 2002, 114, 1342;
4. Angew. Chem. Int. Ed. 2002, 41, 1290;
5. C. M. Crudden, D. P. Allen, Coord. Chem. Rev. 2004,248, 2247;
6. E. Peris, R. H. Crabtree, Coord. Chem. Rev. 2004, 248, 2239;
7. E. Peris, R. H. Crabtree, C. R. Chim. 2003, 6, 33;
8. J. A. Mata, M. Poyatos, E. Peris, Coord. Chem. Rev. 2007, 251, 841-859.
9. S. Gründemann, A. Kovacevic, M. Albrecht, J. W. Faller, R. H. Crabtree, Chem. Commun. 2001, 2274;
10. S. Grundemann, A. Kovacevic, M. Albrecht, J. W. Faller, R. H. Crabtree, J. Am. Chem. Soc. 2002, 124, 10473;
11. A. Kovacevic, S. Gründemann, J. R. Miecznikowski, E. Clot, O. Eisenstein, R. H. Crabtree, Chem. Commun. 2002, 2580;
12. L. N. Appelhans, D. Zuccaccia, A. Kovacevic, A. R. Chianese, J. R. Miecznikowski, A. Macchioni, E. Clot, O. Eisenstein, R. H. Crabtree, J. Am. Chem. Soc. 2005, 127, 16299.
13. A. J. Boydston, C. W. Bielawski, Dalton Trans. 2006, 4073;
14. D. M. Khramov, A. J. Boydston, C. W. Bielawski, Angew. Chem. 2006, 118, 6332;
15. Angew. Chem. Int. Ed. 2006, 45, 6186;
16. A. J. Boydston, K. A. Williams, C. W. Bielawski, J. Am. Chem. Soc. 2005, 127, 12496.
17. T. J. Curphey, K. S. Prasad, J. Org. Chem. 1972, 37, 2259.
18. O. Guerret, S. Sole, H. Gornitzka, G. Trinquier, G. Bertrand, J. Organomet. Chem. 2000, 600, 112.
19. O. Guerret, S. Sole, H. Gornitzka, M. Teichert, G. Trinquier, G. Bertrand, J. Am. Chem. Soc. 1997, 119, 6668.
20. W. A. Herrmann, J. Schutz, G. D. Frey, E. Herdtweck, Organometallics 2006, 25, 2437.
21. C. A. Tolman, Chem. Rev. 1977, 77, 313.
22. A. R. Chianese, X. W. Li, M. C. Janzen, J. W. Faller, R. H. Crabtree, Organometallics 2003, 22, 1663.
23. A. R. Chianese, A. Kovacevic, B. M. Zeglis, J. W. Faller, R. H. Crabtree, Organometallics 2004, 23, 2461.
24. D. Gnanamgari, A. Moores, E. Rajaseelan, R. H. Crabtree, Organometallics 2007, 26, 1226-1230.
25. A. C. Hillier, H. M. Lee, E. D. Stevens, S. P. Nolan, Organometallics 2001, 20, 4246.
26. E. Mas-Marza, E. Peris, I. Castro-Rodriguez, K. Meyer, Organometallics 2005, 24, 3158.
27. E. Mas-Marza, M. Sanau, E. Peris, Inorg. Chem. 2005, 44, 9961.
28. S. Burling, L. D. Field, H. L. Li, B. A. Messerle, P. Turner, Eur. I. Inorg. Chem. 2003, 3179;
29. S. Elgafi, L. D. Field, B. A. Messerle, J. Organomet. Chem. 2000, 607, 97.
30. CCDC-635919 (2) and CCDC-635920 (4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.