Synthesis and structure of 1,2,4-triazol-2-ium-5-ylidene complexes of Hg(II), Pd(II), Ni(II), Ni(0), Rh(I) and Ir(I)

Journal of Organometallic Chemistry

Volumn 664, Issue 1-2, 2002, Pages 70-76

  Buron, Christophe ^a   Stelzig, Lutz ^a   Guerret, Olivier ^a   Gornitzka, Heinz ^a   Romanenko, Vadim ^b   Bertrand, Guy ^a,b  

^a UMR 5069) 118 route de Narbonne   (France)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

1,2,4 Triazol 2 ium 5 ylidene complexes; N heterocyclic carbene ligand; Synthesis

Indexed keywords

1,2,4 TRIAZOLE DERIVATIVE; CARBENOID; CARBON MONOXIDE; CARBONYL DERIVATIVE; CATION; HETEROCYCLIC NITRO COMPOUND; IRIDIUM COMPLEX; LIGAND; MERCURY DERIVATIVE; NICKEL COMPLEX; PALLADIUM COMPLEX; RHENIUM COMPLEX; WATER; ZINC;

CHEMICAL STRUCTURE; COMPLEX FORMATION; CONTROLLED STUDY; CRYSTAL STRUCTURE; REDUCTION; REVIEW; SOLUBILITY; SYNTHESIS; X RAY DIFFRACTION;

EID: 0037121807     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(02)01924-1     Document Type: Article

References (48)

1. B. Cornils, W.A. Herrmann, Aqueous-Phase Organometallic Catalysis, Wiley-VCH, Weinheim, 1998.
2. G. Fremy, Y. Castanet, R. Grzybek, E. Monflier, A. Mortreux, A.M. Trzeciak, J.J. Ziólkowski, J. Organomet. Chem. 505 (1995) 11;
3. J.X. Gao, P.P. Xu, X.D. Yi, H.L. Wan, K.R. Tsai, J. Mol. Cat. A: Chem. 147 (1999) 99;
4. A. Fukuoka, W. Kosugi, F. Morishita, M. Hirano, L. McCaffrey, W. Henderden, S. Komiga, Chem. Commun. (1999) 489;
5. E. Mieczynska, A.M. Trzeciak, J.J. Ziólkowski, J. Mol. Cat. A: Chem. 148 (1999) 59;
6. B. Cornils, J. Mol. Cat. A: Chem. 143 (1999) 1;
7. A.M. Trzeciak, J.J. Ziólkowski, Coord. Chem. Rev. 190-192 (1999) 883;
8. T. Borrmann, H.W. Roesky, U. Ritter, J. Mol. Cat. A: Chem. 153 (2000) 31;
9. S. Paganelli, M. Zanchet, M. Marchetti, G. Mangano, J. Mol. Cat. A: Chem. 157 (2000) 1.
10. M. Beller, J.G.E. Krauter, A. Zapf, Angew. Chem. Int. Ed. Engl. 36 (1997) 772;
11. J.P. Genêt,M. Savignac, J. Organomet. Chem. 576 (1999) 305.
12. T.A. Kirkland, D.M. Lynn, R.H. Grubbs, J. Org. Chem. 63 (1998) 9904;
13. D.M. Lynn, B. Mohr, R.H. Grubbs, L.M. Henling, M.W. Day, J. Am. Chem. Soc. 122 (2000) 6601;
14. M. Saoud, A. Romerosa, M. Peruzzini, Organometallics 19 (2000) 4005;
15. T.M. Trnka, R.H. Grubbs, Acc. Chem. Res. 34 (2001) 18.
16. P. Kalck, F. Monteil, Adv. Organomet. Chem. 34 (1992) 219;
17. W.A. Herrmann, C.W. Kohlpainter, Angew. Chem. Int. Ed. Engl. 32 (1993) 1524;
18. B. Cornils, Angew. Chem. Int. Ed. Engl. 34 (1995) 1575.
19. D. Bourissou, O. Guerret, F.P. Gabbaï, G. Bertrand, Chem. Rev. 100 (2000) 39.
20. L. Jafarpour, S.P. Nolan, Adv. Organomet. Chem. 46 (2001) 181.
21. W.A. Herrmann, Angew. Chem. Int. Ed. Engl. 41 (2002) 1291.
22. S.T. Liu, R.Z. Ku, L.Y. Liu, F.M. Kiang, J. Organomet. Chem. 543 (1997) 249.
23. W.A. Herrmann, L.J. Goossen, M. Spiegler, J. Organomet. Chem. 547 (1997) 357.
24. H.G.O. Becker, G. Hoffmann, K.M. Gwar, L. Knüpfer, J. Prakt. Chem. 330 (1988) 325;
25. R. Noto, G. Buccheri, G. Cusmano, M. Gruttadauria, G.J. Werber, Heterocycl. Chem. 28 (1991) 1421.
26. H.J. Schönherr, H.W. Wanzlick, Chem. Ber. 103 (1970) 1037.
27. A.J. Arduengo, R.L. Harlow, W.J. Marshall, T.K. Prakasha, Heteroatom Chem. 7 (1996) 421.
28. B. Bildstein, M. Malaun, H. Kopacka, K.-H. Ongania, K.J. Wurst, Organomet. Chem. 552 (1998) 45;
29. B. Bildstein, M. Malaun, H. Kopacka, K.-H. Ongania, K. Wurst, J. Organomet. Chem. 572 (1999) 177;
30. J.C.C. Chen, I.J.B. Lin, J. Chem. Soc. Dalton Trans. (2000) 839;
31. K.-M. Lee, J.C.C. Chen, I.J.B. Lin, J. Organomet. Chem. 617-618 (2001) 364.
32. H. Wanzlick, H.J. Schönherr, Angew. Chem. Int. Ed. Engl. 7 (1968) 141;
33. V.P. Luger, G. Ruban, Acta Crystallogr. Sect. B 27 (1971) 2276.
34. C.K. Lee, J.C.C. Chen, C.M. Liu, I.J.B. Lin, Chem. Mater. 11 (1999) 1237.
35. W.A. Herrmann, T. Weskamp, V.P.W. Böhm, Adv. Organomet. Chem. 48 (2001) 1.
36. D. Enders, H. Gielen, G. Raabe, J. Runsink, J.H. Teles, Chem. Ber. 129 (1996) 1483;
37. W.A. Herrmann, J. Fisher, K. Öfele, G.R.J. Artus, J. Organomet. Chem. 530 (1997) 259;
38. L. Xu, W. Chen, J.F. Bickley, A. Steiner, J. Xiao, J. Organomet. Chem. 598 (2000) 409.
39. W.A. Herrmann, M. Elison, J. Fisher, C. Koecher, G. Artus, Chem. Eur. J. 2 (1996) 772.
40. K. Öfele, W.A. Herrmann, D. Mihalios, M. Elison, E. Herdtweck, W. Scherer, J. Mink, J. Organomet. Chem. 439 (1993) 177;
41. W.A. Herrmann, L.J. Goossen, C. Köcher, G.R.J. Artus, Angew. Chem. Int. Ed. Engl. 35 (1996) 2805;
42. W.A. Herrmann, L.J. Goossen, G.R.J. Artus, C. Köcher, Organometallics 16 (1997) 2472;
43. P.L. Arnold, F.G.N. Cloke, T. Geldbach, P.B. Hitchcock, Organometallics 18 (1999) 3228;
44. M.F. Lappert, P.L. Pye, J. Chem. Soc. Dalton Trans. (1977) 2172.
45. - (saturated calomel electrode reference): E = 0.2674 V. See: Vanycek, P. In: D.E. Lindr (ed.), CRC Handbook of Chemistry and Physics; 75th ed., CRC Press, Bosa Raton, 1994, pp. 8-21.
46. G. Bertrand, L. Stelzig, O. Guerret, C. Buron, H. Gornitzka, P. Burattin, Organometallic Complexes Containing Cationic 1,2,4-Triazolium-5-ylidene Heterocyclic Carbene Ligands and Their Catalytic Activity. WO99/60004 (November 25, 1999); C.A. 1999, 131, 351465.
47. G.M. Sheldrick, Acta Crystallogr. Sect. A 46 (1990) 467.
48. G.M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, Universitat Goöttingen, 1997.