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Volumn 111, Issue 33, 2007, Pages 12407-12413

Characterizing chemically reactive thin layers: Surface reaction of [2-[4-(chlorosulfonyl)phenyl]ethyl]trichlorosilane with Ammonia

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; BIOMOLECULES; CATALYSTS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; REACTION KINETICS; SURFACE PROPERTIES; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 34548551170     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp072784+     Document Type: Article
Times cited : (11)

References (52)
  • 2
  • 38
    • 2142780806 scopus 로고
    • Wagner, C. D, Riggs, W. M, Davis, L. E, Moulder, J. F, Muilenberg, G. E, Eds, Perkin-Elmer Corp, Waltham, MA
    • Wagner, C. D., Riggs, W. M., Davis, L. E., Moulder, J. F., Muilenberg, G. E., Eds. Handbook of X-Ray Photoelectron Spectroscopy; Perkin-Elmer Corp.: Waltham, MA, 1978.
    • (1978) Handbook of X-Ray Photoelectron Spectroscopy
  • 41
    • 34548594937 scopus 로고    scopus 로고
    • Frisch, M. J, Trucks, G. W, Schlegel, H. B, Scuseria, G. E, Robb, M. A, Cheeseman, J. R, Montgomery, J. A, Jr, Vreven, T, Kudin, K. N, Burant, J. C, Millam, J. M, Iyengar. S. S, Tomasi, J, Barone, V, Mennucci, B, Cossi, M, Scalmani, G, Rega, N, Petersson, G. A, Nakatsuji, H, Hada, M, Ehara, M, Toyota. K, Fukuda, R, Hasegawa, J, Ishida, M, Nakajima, T, Honda, Y, Ritao, O, Nakai, H, Klene, M, Li, X, Knox, J. E, Hratchian, H. P, Cross. J. B, Adamo, C, Jaramillo, J, Gomperts, R, Stratmann, R. E, Yazyev, O, Austin, A. J, Cammi, R, Pomelli, C, Ochterski, J. W, Ayala, P. Y, Morokuma, K, Voth, G. A, Salvador, P, Dannenberg, J. J, Zakrzewski, V. G, Dapprich, S, Daniels, A. D, Strain, M. C, Farkas, O, Malick. D. R, Rabuck, A. D, Raghavachari, K, Foresman, J. B, Ortiz. J. V, Cui, Q, Baboul, A. G, Clifford, S, Cioslowski, J, Stefanov, B. B, Liu, G, Liashenko, A, Piskorz, P, Komaromi, I, Martin, R. L, Fox, D. J, Keith, T, Al-La
    • Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Montgomery, J. A., Jr.; Vreven, T.; Kudin, K. N.; Burant, J. C.; Millam, J. M.; Iyengar. S. S.; Tomasi, J.; Barone, V.; Mennucci, B.; Cossi, M.; Scalmani, G.: Rega, N.; Petersson, G. A.; Nakatsuji, H.; Hada, M.; Ehara, M.; Toyota. K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Ritao, O.; Nakai, H.; Klene, M.; Li, X.; Knox, J. E.; Hratchian, H. P.; Cross. J. B.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Ayala, P. Y.; Morokuma, K.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Zakrzewski, V. G.; Dapprich, S.; Daniels, A. D.; Strain, M. C.; Farkas, O.; Malick. D. R.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Ortiz. J. V.; Cui, Q.; Baboul, A. G.; Clifford, S.; Cioslowski, J.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C Y.; Nanayakkara, A.; Challacombe. M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Gonzalez. C.; Pople, J. A. Gaussian 03, Revision C.02; Gaussian, Inc.: Wallingford, CT, 2004.
  • 42
    • 34548555387 scopus 로고    scopus 로고
    • For the theoretical calculations, molecules containing trichlorosilane anchoring groups have been chosen, although in the experiment these groups will eventually react with the SiOH groups, anchoring the molecules to the surface
    • For the theoretical calculations, molecules containing trichlorosilane anchoring groups have been chosen, although in the experiment these groups will eventually react with the SiOH groups, anchoring the molecules to the surface.
  • 43
    • 34548594938 scopus 로고    scopus 로고
    • The keywords opt, verytight and int, ultrafine were used
    • The keywords "opt = verytight" and "int = ultrafine" were used.
  • 44
    • 34548569668 scopus 로고    scopus 로고
    • Ochterski, J. W. Gaussian White Paper, Vibrational Analysis in Gaussian; Gaussian, Inc.: Wallingford, CT, 1999.
    • Ochterski, J. W. Gaussian White Paper, Vibrational Analysis in Gaussian; Gaussian, Inc.: Wallingford, CT, 1999.
  • 45
    • 34548552292 scopus 로고    scopus 로고
    • 2 atmosphere range from 2.0 to 2.6 nm. Varying the immersion time between 4 and 20 h does not result in a significant difference in film thickness (variations up to approximately 10%). Very short times (30 min) lead to thinner films, at the price of a less densely packed layer(s). Films prepared under ambient conditions, however, show a strong dependence on external parameters such as the humidity and water content of the solvent.
    • 2 atmosphere range from 2.0 to 2.6 nm. Varying the immersion time between 4 and 20 h does not result in a significant difference in film thickness (variations up to approximately 10%). Very short times (30 min) lead to thinner films, at the price of a less densely packed layer(s). Films prepared under ambient conditions, however, show a strong dependence on external parameters such as the humidity and water content of the solvent.
  • 48
    • 34548563512 scopus 로고    scopus 로고
    • In contrast to the contact angle measurements (measurement times less than 2 s) hydrolysis of sulfonyl chlorides takes place during the equilibration phase before the first measurement point of the ζ-potential
    • In contrast to the contact angle measurements (measurement times less than 2 s) hydrolysis of sulfonyl chlorides takes place during the equilibration phase before the first measurement point of the ζ-potential.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.