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Complete X-ray crystallographic data are provided in the Supporting Information
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Complete X-ray crystallographic data are provided in the Supporting Information.
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The unsubstituted sulfonamide 5a is not observed during the thermolysis of 1a with added 3a.
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The unsubstituted sulfonamide 5a is not observed during the thermolysis of 1a with added 3a.
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The dimer 10a contains two sulfonamide moieties and forms from 2 equiv of the starting material 1a.
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The dimer 10a contains two sulfonamide moieties and forms from 2 equiv of the starting material 1a.
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34548205869
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The rate law for the C-N reductive elimination reaction pathway shown in Scheme 7 (also path D, Scheme 6) simplifies to the following: rate, kC-N[1a, where kC-N, k 1k2, k2, k -1, This rate law is independent of [NHSO2R, See ref 10
-
-]. See ref 10.
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0037164632
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34548280408
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3 resonance of the butyl chain.
-
3 resonance of the butyl chain.
-
-
-
|