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Volumn 129, Issue 34, 2007, Pages 10382-10393

Alkyl carbon-nitrogen reductive elimination from platinum(IV)-sulfonamide complexes

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE; CARBON; CATALYST SELECTIVITY; ETHANE; NITROGEN; THERMOLYSIS;

EID: 34548207715     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja069191h     Document Type: Article
Times cited : (92)

References (90)
  • 13
    • 34548209275 scopus 로고    scopus 로고
    • Seeref 2f
    • (d) Seeref 2f.
  • 52
    • 34548219559 scopus 로고    scopus 로고
    • Complete X-ray crystallographic data are provided in the Supporting Information
    • Complete X-ray crystallographic data are provided in the Supporting Information.
  • 56
    • 34548246039 scopus 로고    scopus 로고
    • The unsubstituted sulfonamide 5a is not observed during the thermolysis of 1a with added 3a.
    • The unsubstituted sulfonamide 5a is not observed during the thermolysis of 1a with added 3a.
  • 59
    • 34548243265 scopus 로고    scopus 로고
    • The dimer 10a contains two sulfonamide moieties and forms from 2 equiv of the starting material 1a.
    • The dimer 10a contains two sulfonamide moieties and forms from 2 equiv of the starting material 1a.
  • 77
    • 0346265937 scopus 로고
    • 2nd ed, Puddephatt, R. J, Ed, Pergamon: New York, Chapter 5
    • (j) Canty, A. J. In Comprehensive Organometallic Chemistry, 2nd ed.; Puddephatt, R. J., Ed.; Pergamon: New York 1995; Vol. 9, Chapter 5.
    • (1995) Comprehensive Organometallic Chemistry , vol.9
    • Canty, A.J.1
  • 84
    • 34548205869 scopus 로고    scopus 로고
    • The rate law for the C-N reductive elimination reaction pathway shown in Scheme 7 (also path D, Scheme 6) simplifies to the following: rate, kC-N[1a, where kC-N, k 1k2, k2, k -1, This rate law is independent of [NHSO2R, See ref 10
    • -]. See ref 10.
  • 89
    • 34548280408 scopus 로고    scopus 로고
    • 3 resonance of the butyl chain.
    • 3 resonance of the butyl chain.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.