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Volumn 307, Issue 5712, 2005, Pages 1080-1082

Oxidative addition of ammonia to form a stable monomeric amido hydride complex

Author keywords

[No Author keywords available]

Indexed keywords

AMINATION; AMMONIA; CATALYSIS; CHEMICAL BONDS; COMPLEXATION; IRIDIUM COMPOUNDS; MOLECULAR STRUCTURE; OLEFINS; OXIDATION; PHOSPHORUS; REACTION KINETICS;

EID: 13844307699     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.1109389     Document Type: Article
Times cited : (385)

References (30)
  • 1
    • 13844320922 scopus 로고
    • American Chemical Society Symposium Series, Washington, DC
    • G. B. Kauffman, In Coordination Chemistry: A Century of Progress. (American Chemical Society Symposium Series, Washington, DC, 1994), vol. 565, pp. 3-34.
    • (1994) Coordination Chemistry: A Century of Progress , vol.565 , pp. 3-34
    • Kauffman, G.B.1
  • 2
    • 33751385366 scopus 로고
    • Two reactions of ammonia are among the top 10 challenges for catalysis listed in this article: J. Haggin, Chem. Eng. News. 71, 23 (1993).
    • (1993) J. Haggin, Chem. Eng. News. , vol.71 , pp. 23
  • 4
    • 0021500127 scopus 로고
    • For the protonolysis of a hydride ligand on a group IV metal complex, presumably after coordination of the ammonia ligand, see G. L. Hillhouse, J. E. Bercaw, J. Am. Chem. Soc. 106, 5472 (1984).
    • (1984) J. Am. Chem. Soc. , vol.106 , pp. 5472
    • Hillhouse, G.L.1    Bercaw, J.E.2
  • 20
    • 13844316999 scopus 로고    scopus 로고
    • note
    • Materials and methods, Including the details of the synthesis of the olefin complexes, are available as supporting material on Science Online.
  • 29
    • 13844309964 scopus 로고    scopus 로고
    • note
    • This method would detect deuterium in the ligand if it were present in 10% of the sample.
  • 30
    • 13844308317 scopus 로고    scopus 로고
    • We thank the Department of Energy for funding. Structural data for compounds 4a and 5 have been deposited in the Cambridge Crystallographic Data Centre under CCDC 260224 (4a) and 260225 (5), and can be obtained free of charge at www.ccdc.cam. ac.uk/conts/retrieving.html. We thank L. Bienen for editing of the manuscript.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.