Indoline synthesis via coupling of phenethyl grignard reagents with organoazides mediated by (alkylphosphine)nickel(II) complexes

Organometallics

Volumn 15, Issue 12, 1996, Pages 2669-2671

  Koo, Kwangmo ^a   Hillhouse, Gregory L ^a  

^a UNIVERSITY OF CHICAGO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 5844364898     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960286+     Document Type: Article

References (26)

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14. The thermal decomposition of 1 does not yield 2 but rather products derived from β-hydrogen eliminations: Zhong, A.; Koo, K.; Hillhouse, G. L. Unpublished results.
15. (a) Guram, A. S.; Buchwald, S. L. J. Am. Chem. Soc. 1994, 116, 7901.
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19. Complete synthetic procedures and spectral data are reported in the Supporting Information.
20. Koo, K.; Hillhouse, G. L.; Rheingold, A. L. Organometallics 1995, 14, 456.
21. 3Tol are allowed to react with 3, the reaction still proceeds according to eq 3, giving diminished yields of 4a along with unreacted 3.
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25. 31P NMR spectroscopy (202.5 MHz, δ47.8).
26. 4) was isolated as an orange powder in modest yield.