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Volumn 119, Issue 35, 1997, Pages 8232-8245

Carbon-nitrogen-bond-forming reductive elimination of arylamines from palladium(II) phosphine complexes

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC AMINE; PALLADIUM COMPLEX;

EID: 0030864744     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja971057x     Document Type: Article
Times cited : (275)

References (98)
  • 11
    • 0001687271 scopus 로고
    • Imine hydrogenation catalyzed by rhodium and iridium complexes would be expected to occur through an amide complex. However, mechanistic data is scarce. A direct observation of imine insertion that produces an amide complex potentially similar to those in catalytic systems is the following: Fryzuk, M. D.; Piers, W. E. Organometallics 1990, 9, 986-98.
    • (1990) Organometallics , vol.9 , pp. 986-998
    • Fryzuk, M.D.1    Piers, W.E.2
  • 12
    • 0000041989 scopus 로고
    • For a recent review see: James, B. R. Chem. Ind. 1995, 62, 167-180.
    • (1995) Chem. Ind. , vol.62 , pp. 167-180
    • James, B.R.1
  • 35
    • 3743092578 scopus 로고
    • and references therein
    • Bryndza, H. E.; Tam, W. Chem. Rev. 1988, 88, 1163 and references therein.
    • (1988) Chem. Rev. , vol.88 , pp. 1163
    • Bryndza, H.E.1    Tam, W.2
  • 62
    • 1842404031 scopus 로고    scopus 로고
    • note
    • 1H NMR, GC retention time, and GC/MS were compared to an authentic commercial sample. In pp .
  • 75
    • 1842365925 scopus 로고    scopus 로고
    • note
    • Reductive elimination and aryl group exchange are competing, but separate processes. Their dependence on ligand concentration identity is markedly different. Please see the following three references.
  • 82
    • 1842289051 scopus 로고    scopus 로고
    • note
    • 1H NMR signals for the t-Bu peaks were distinguishable at 50°C: 6a δ 1.237 ppm; 6b δ 1.218 ppm; 6c δ 1.228 ppm and 1.226 ppm.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.